Chlorocalcite

KCaCl3
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ccal
Discovered
1872
Also known as
  • Baeumlerit
  • Baeumlerita
  • Baeumlerite
  • +7 more

Where it forms, where it's found

Geological setting

Active volcanic fumaroles.

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
White · violet tinged
Cleavage
Distinct/Good

Cube-like in two directions, one better than the other.

Optical

Optical type
Biaxial
Refractive index
1.52
Surface relief
Moderate
Principal indices
nβ 1.52
Dispersion
not discernible
UV response
None.

Crystallography

Crystal system
Orthorhombic
Space group
Pnma
Cell parameters
a = 7.35 Å · b = 10.44 Å · c = 7.25 Å
Ratio a:b:c
1 : 1.420 : 0.986
Morphology

Cube-like crystals, with octahedral or dodecahedral-like truncations at times. Prismatic with (100), (010), and (011) or tabular with (001), (110), and (100).

Comment

Space group for the synthetic phase

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
17ClChlorineChlorine335.450106.350
57.32%
20CaCalciumCalcium140.07840.078
21.60%
19KPotassiumPotassium139.09839.098
21.08%
Total185.526100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Baeumlerit
  • Baeumlerita
  • Baeumlerite
  • Bäumlerit
  • Bäumlerita
  • Bäumlerite
  • Chlorocalciet
  • Chlorocalcita
  • Clorocalcit
  • Idroclorato di calce in piccola dose

In other languages

German
Chlorocalcit
Italian
clorocalcite
Arabic
كلوروكالسيت

Classification

Strunz
10th ed.

3.AA.40

  • 3HalidesClass
  • 3.ASimple halides, without H2ODivision
  • 3.AAM:X = 1:1, 2:3, 3:5, etc.Group
  • 3.AA.40ChlorocalciteSpecies
Dana
8th ed.

11.01.03.01

  • 11Halide ComplexesClass
  • 11.01AmBX3Type
  • 11.01.03— unnamed intermediate level —Group
  • 11.01.03.01ChlorocalciteSpecies
CIM

8.4.10

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.4Halides of the alkaline earths and MgGroup
  • 8.4.10ChlorocalciteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1823Monticelli, T. and Covelli, N. (1823) Storia di fenom. Del Vesuvio avven. Negli anni, 1821, etc., Naples: 183.
  2. 1832Beudant, François-Sulpice (1832) Traité élémentaire de minéralogie. Deuxiéme Edition [Elementary Treatise on Mineralogy. Second Edition] (2nd ed.) Vol. 2 - Tome II [Volume II]. Chez Verdière.
  3. 1872Scacchi, A. (1872) Notizie preliminari di alcune specie mineralogiche rinvenute nel Vesuvio dopo l'incendio di aprile 1872. Rendiconto dell'Accademia delle Scienze Fisiche e Matematiche (sezione della Societa reale di Napoli): 11: 210-213.
  4. 1873Scacchi, A. (1873) Reale accademia delle scienze fisische e matematiche, Naples, Mem.: Dec. 13, 1873.
  5. 1907Lacroix, A. (1907) Les minéraux des fumerolles de l'éruption de Vésuve en avril 1906. Bulletin de la Société Française de Minéralogie et de Cristallographie, 30, 219-266 (255).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Chlorocalcite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/chlorocalcite-1020},
  note      = {Accessed 2026-05-11}
}