Chlorothionite

K2Cu(SO4)Cl2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ctn
Discovered
1872
Also known as
  • Chlorothioniet
  • Clorothionita

Where it forms, where it's found

Geological setting

Active volcanic fumaroles.

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Bright blue.
Density
2.67 g/cm³

Optical

Optical type
Biaxial (+)

Crystallography

Crystal system
Orthorhombic
Space group
#71
Cell parameters
a = 7.73 Å · b = 6.07 Å · c = 16.29 Å
Ratio a:b:c
1 : 0.785 : 2.107
Morphology

Crystalline incrustations.

Type-locality form

Bright blue crystalline incrustations.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
19KPotassiumPotassium239.09878.196
25.33%
17ClChlorineChlorine235.45070.900
22.97%
8OOxygenOxygen415.99963.996
20.73%
29CuCopperCopper163.54663.546
20.58%
16SSulfurSulfur132.06032.060
10.39%
Total308.698100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Chlorothioniet
  • Clorothionita

In other languages

German
Chlorothionit
Italian
Chlorothionite · Clorotionite

Classification

Strunz
10th ed.

7.BC.25

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BCWith medium-sized and large cationsGroup
  • 7.BC.25ChlorothioniteSpecies
Dana
8th ed.

30.01.11.01

  • 30Anhydrous Sulfates Containing Hydroxyl or HalogenClass
  • 30.01(AB)m(XO4)pZq, where m:p>2:1Type
  • 30.01.11— unnamed intermediate level —Group
  • 30.01.11.01ChlorothioniteSpecies
CIM

26.6

  • 26Sulphates with HalideClass
  • 26.6— unnamed intermediate level —Group
  • 26.6ChlorothioniteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1872Scacchi, A. (1872) Notizie preliminari di alcune specie mineralogiche rinvenute nel Vesuvio dopo l'incendio di aprile 1872. Rendiconto dell'Accademia delle Scienze Fisiche e Matematiche (sezione della Societa reale di Napoli): 11: 210-213.
  2. 1872Scacchi (1872) Acc. Napoli, Rendus: 203.
  3. 1874Scacchi, A. (1874) Contribuzioni mineralogiche per servire alla storia dell’ incendio Vesuviano del Mese di Aprile, 1872. Part 2. Atti della Reale Accademia delle Scienze Fisiche e Matematiche di Napoli, Serie II: 6: 1-69.
  4. 1910Zambonini, Ferruccio (1910) Mineralogia Vesuviana. 368 pp., Naples: 329 (artificial crystals).
  5. 1913(1913) Atlas Der Krystallformen Vol. 2 - Text - Band II - Calaverit-Cyanochroit. Carl Winters Universitätsbuchhandlung, Heidelberg.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Chlorothionite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/chlorothionite-982},
  note      = {Accessed 2026-05-11}
}