Chloroxiphite

Pb3CuO2Cl2(OH)2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cxp
Discovered
1923
Also known as
  • Chloro-ziphite
  • Chloroxiphiet
  • Chloroxiphita

Where it forms, where it's found

Type locality
Higher Pitts Mine
  1. Priddy
  2. Mendip
  3. Somerset
  4. England
  5. UK

51.2387°, -2.6676°

8recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Resinous to Adamantine
Transparency
Transparent
Colour
Dull olive green
Streak
Light green yellow
Tenacity
very brittle
Cleavage
Perfect

On (101) perfect; (100) distinct.

Density
6.76 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 70° · 2V calc = 36°
Refractive index
2.16 – 2.25
Surface relief
Very high
Principal indices
nα 2.16 · nβ 2.24 · nγ 2.25
Pleochroism
Visible

X ≈ perpendicular to <mi>{_101}</mi> Y = brown Z = b = green

Dispersion
extreme
Michel-Lévy diagramhighlighted lineδ = 0.0900
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]900 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation900 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#15
Cell parameters
a = 6.6972(8) Å · b = 5.7538(5) Å · c = 10.4686(14) Å
Cell angles
β = 97.747(10) °
Ratio a:b:c
1 : 0.859 : 1.563
Unit cell volume
399.72 ų
Morphology

Crystals bladed, elongated [010] and flattened (101). Subparallel groups. (101) roughly striated [010].

Type-locality form

Green, blade-like crystals embedded in mendipite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead3207.200621.600
75.62%
17ClChlorineChlorine235.45070.900
8.62%
8OOxygenOxygen415.99963.996
7.78%
29CuCopperCopper163.54663.546
7.73%
1HHydrogenHydrogen21.0082.016
0.25%
Total822.058100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Chloro-ziphite
  • Chloroxiphiet
  • Chloroxiphita

In other languages

French
chloroxiphite
German
Chloroxiphit
Spanish
Cloroxifita
Italian
chloroxiphite · cloroxifite

Classification

Strunz
10th ed.

3.DB.30

  • 3HalidesClass
  • 3.DOxyhalides, hydroxyhalides and related double halidesDivision
  • 3.DBWith Pb, Cu, etc.Group
  • 3.DB.30ChloroxiphiteSpecies
Dana
8th ed.

10.06.04.01

  • 10Oxyhalides and HydroxyhalidesClass
  • 10.06AmBn(O,OH)pXqType
  • 10.06.04— unnamed intermediate level —Group
  • 10.06.04.01ChloroxiphiteSpecies
CIM

8.8.15

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.8Halides of PbGroup
  • 8.8.15ChloroxiphiteSpecies

Literature, links & citation

Citations
  1. 1923Spencer, L. J. (1923) New lead-copper minerals from the Mendip Hills (Somerset) Mineralogical Magazine and Journal of the Mineralogical Society, 20 (102) 67-92 doi:10.1180/minmag.1923.020.102.01 DOI: 10.1180/minmag.1923.020.102.01
  2. 1924Wherry, E.T. (1924) New minerals: new species. American Mineralogist: 9: 96-97.
  3. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  4. 1977Finney, J. J., Graeber, E. J., Rosenzweig, A., Hamilton, R. D. (1977) The structure of chloroxiphite, Pb3CuO2(OH)2Cl2. Mineralogical Magazine, 41 (319) 357-361 doi:10.1180/minmag.1977.041.319.07 DOI: 10.1180/minmag.1977.041.319.07
  5. 1980Alun Humphreys, D., Thomas, John H., Williams, Peter A., Symes, Robert F. (1980) The chemical stability of mendipite, diaboleïte, chloroxiphite, and cumengéite, and their relationships to other secondary lead(II) minerals. Mineralogical Magazine, 43 (331) 901-904 doi:10.1180/minmag.1980.043.331.13 DOI: 10.1180/minmag.1980.043.331.13
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Chloroxiphite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/chloroxiphite-953},
  note      = {Accessed 2026-05-11}
}