Cation by cation.
The subgroup axis is almost always the dominant cation — Cu, Mg, Ca, Fe, Mn, Ni, the rare earths. Chemistry decides the bin before crystallography is even consulted.
Hey's index sorts every mineral by the cations and anions it actually carries — group first, then subgroup. Tap any branch in the tree to surface its catalogued species.
The subgroup axis is almost always the dominant cation — Cu, Mg, Ca, Fe, Mn, Ni, the rare earths. Chemistry decides the bin before crystallography is even consulted.
Group · subgroup · species — only three positions in the address. Chloritoid is 16.19.6: group 16 (Aluminum-bearing silicates), subgroup 19 (with Fe and Mg), species 6.
Mindat froze its Hey index when Strunz absorbed the maintenance workload — the taxonomy still ships, the curation moved next door. Useful as a chemistry-first cross-reference; not the current authority on new species.