Clairite

(NH4)2Fe3+3(SO4)4(OH)3 · 3H2O
IMA status
  • Approved
IMA symbol
Clai
Discovered
1982
IMA approved
1982
Also known as
  • Clairiet
  • IMA1982-093

Where it forms, where it's found

Geological setting

Alteration of pyrite and decaying organic material (Hyrex excreta).

Type locality
Lone Creek Falls cave
  1. Lone Creek Falls
  2. Sabie
  3. Thaba Chweu Local Municipality
  4. Ehlanzeni District Municipality
  5. Mpumalanga
  6. South Africa

-25.1022°, 30.7092°

10recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent · Translucent
Colour
Orange-Yellow
Density
2.31 g/cm³

Optical

Optical type
Biaxial
Refractive index
1.595 – 1.607
Surface relief
Moderate
Principal indices
nα 1.595 · nγ 1.607
Pleochroism
Weak

X= pale yellow Z'= dark yellow

Dispersion
r > v or r < v
Michel-Lévy diagramhighlighted lineδ = 0.0120
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]120 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation120 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Cell parameters
a = 9.36 Å · b = 9.15 Å · c = 52.61 Å
Cell angles
α = 88.15 ° · β = 90 ° · γ = 118.36 °
Ratio a:b:c
1 : 0.978 : 5.621
Morphology

Powdery aggregates of pseudo-hexagonal plates.

Comment

point group _1 or 1; space group P_1 or P1

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2215.999351.978
50.80%
26FeIronIron355.845167.535
24.18%
16SSulfurSulfur432.060128.240
18.51%
7NNitrogenNitrogen214.00728.014
4.04%
1HHydrogenHydrogen171.00817.136
2.47%
Total692.903100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Clairiet
  • IMA1982-093

In other languages

German
Clairit · IMA 1982-093
Italian
Clairite
Chinese
科拉里矾

Classification

Strunz
10th ed.

7.DF.55

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DFWith large and medium-sized cationsGroup
  • 7.DF.55ClairiteSpecies
Dana
8th ed.

31.10.08.01

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.10MiscellaneousType
  • 31.10.08— unnamed intermediate level —Group
  • 31.10.08.01ClairiteSpecies
CIM

25.11.15

  • 25SulphatesClass
  • 25.11Sulphates of Fe and other metalsGroup
  • 25.11.15ClairiteSpecies

Literature, links & citation

Citations
  1. 1984Martini, J.E.J. (1984) Lonecreekite, sabieite, and clairite, new secondary ammonium ferric-iron sulfates from Lone Creek Fall cave, near Sabie, eastern Transvaal. Annals of the Geological Survey (South Africa): 17: 29-34.
  2. 1986Dunn, Pete J., Chao, George Y., Fitzpatrick, Joan J., Langley, Richard H., Fleischer, Michael, Zilczer, Janet A. (1986) New Mineral Names. American Mineralogist, 71 (1-2). 227-232
  3. 1997Daltry, V. D. C. (1997) Mineralogy of South Africa: Type-Mineral Species and Type-Mineral Names. Handbook 15. Geological Survey of South Africa
  4. 2005(2005) Clairite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2020Košek, F., Edwards, H.G.M., Jehlička, J. (2020) Raman spectroscopic vibrational analysis of the complex iron sulfates clairite, metavoltine, and voltaite from the burning coal dump Anna I, Alsdorf, Germany. Journal of Raman Spectroscopy, 51 (9) 1454-1461 doi:10.1002/jrs.5625DOI: 10.1002/jrs.5625
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Clairite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/clairite-1056},
  note      = {Accessed 2026-05-11}
}