Cuprocherokeeite

[Pb8Zn3Cu2+(OH)16](SO4)4 · 4H2O
IMA status
  • Approved
IMA symbol
Cchk
Also known as
  • Cuprocherokeeiet
  • IMA2022-086

Where it forms, where it's found

Geological setting

"highly unusual secondary assemblage that comprises a variety of rare Pb-Zn-Cu sulfates, thiosulfates, and carbonates"

Type locality
Redmond Mine
  1. Waterville Lake
  2. Haywood County
  3. North Carolina
  4. USA

35.6802°, -83.0186°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
light blue
Streak
very pale bluish-white
Tenacity
brittle
Cleavage
Distinct/Good

probable, 2 directions

Fracture
Irregular/Uneven

Optical

Optical type
Biaxial (+) · 2V measured = 65°
Refractive index
1.76 – 1.8
Surface relief
High
Principal indices
nα 1.760 · nβ 1.770 · nγ 1.800
Michel-Lévy diagramhighlighted lineδ = 0.0400
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]400 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation400 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 12.6828(5) Å · b = 9.4629(5) Å · c = 14.7876(8) Å
Cell angles
β = 94.798(4) °
Ratio a:b:c
1 : 0.746 : 1.166
Translation gliding
irregular & curved fracture
Type-locality form

prisms or blades, to ca. 1 mm

Comment

Space group P21/n

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead8207.2001657.600
62.65%
8OOxygenOxygen3615.999575.964
21.77%
30ZnZincZinc365.380196.140
7.41%
16SSulfurSulfur432.060128.240
4.85%
29CuCopperCopper163.54663.546
2.40%
1HHydrogenHydrogen241.00824.192
0.92%
Total2645.682100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Cuprocherokeeiet
  • IMA2022-086

In other languages

German
Cuprocherokeeit · IMA 2022-086

Classification

Strunz
10th ed.

7.DF

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DFWith large and medium-sized cationsGroup
  • 7.DFCuprocherokeeiteSpecies

Literature, links & citation

Citations
  1. 2022Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2022) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 70. European Journal of Mineralogy, 34 (6) 591-601 doi:10.5194/ejm-34-591-2022 DOI: 10.5194/ejm-34-591-2022
  2. 2023Kampf, Anthony R.; Smith, Jason B.; Hughes, John M.; Ma, Chi; Emproto, Christopher (2023) New Minerals from the Redmond Mine, North Carolina, USA: III. Cherokeeite and Cuprocherokeeite, Two New Minerals Containing [Pb2(Zn,Cu2+)(OH)4]2+ Chains. The Canadian Journal of Mineralogy and Petrology, 61 (3). 635-647 doi:10.3749/2300001DOI: 10.3749/2300001
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Cuprocherokeeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/cuprocherokeeite-470493},
  note      = {Accessed 2026-05-11}
}