Cuprodobrovolskyite

Na4Cu(SO4)3
IMA status
  • Approved
IMA symbol
Cdvo
IMA approved
2022
Also known as
  • Cuprodobrovolskyiet
  • IMA2022-061

Where it forms, where it's found

Geological setting

In fumarolic pockets with temperature 350–400°C

Type locality
Arsenatnaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.6833°, 160.2333°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
light blue or greenish-bluish to almost colourless
Streak
white
Density
2.783 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.509 – 1.528
Surface relief
Moderate
Principal indices
nω 1.509 · nε 1.528
Pleochroism
Non-pleochroic
Michel-Lévy diagramhighlighted lineδ = 0.0190
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]190 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation190 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#78
Cell parameters
a = 15.702(2) Å · c = 22.017(2) Å
Z
18
Type-locality form

coarse hexagonal tabular or equant, typically skeletal crystals up to 1 mm and their clusters or crusts up to 1.5 cm × 2.5 cm in area.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
43.27%
16SSulfurSulfur332.06096.180
21.68%
11NaSodiumSodium422.99091.960
20.73%
29CuCopperCopper163.54663.546
14.32%
Total443.674100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Cuprodobrovolskyiet
  • IMA2022-061

In other languages

German
Cuprodobrovolskyit · IMA 2022-061

Classification

Strunz
10th ed.

7.AD

  • 7SulfatesClass
  • 7.ASulfates (selenates, etc.) without additional anions, without H2ODivision
  • 7.ADWith only large cationsGroup
  • 7.ADCuprodobrovolskyiteSpecies

Literature, links & citation

Citations
  1. 2022Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2022) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 70. European Journal of Mineralogy, 34 (6) 591-601 doi:10.5194/ejm-34-591-2022 DOI: 10.5194/ejm-34-591-2022
  2. 2024Shchipalkina, NV, Pekov, IV, Koshlyakova, NN, Belakovskiy, DI, Zubkova, NV, Agakhanov, AA, Britvin, SN, Nazarova, MA (2024) A new mineral cuprodobrovolskyite Na4Cu (SO4) 3 from the Tolbachik volcano (Kamchatka, Russia) and the relations in the family of natural anhydrous Na-Cu sulfates. Min Mag (accepted), 88 (1). 49-60
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Cuprodobrovolskyite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/cuprodobrovolskyite-470489},
  note      = {Accessed 2026-05-11}
}