Davidbrownite-(NH4)

(NH4)5(V4+O)2(C2O4)[PO2.75(OH)1.25]4 · 3H2O
IMA status
  • Approved
IMA symbol
Dbn-NH4
IMA approved
2019
Also known as
  • Davidbrowniet-(NH4)
  • Davidbrownite
  • IMA2018-129

Where it forms, where it's found

Geological setting

Bat-guano-related, post-mining assemblage

Type locality
125 foot level
  1. Rowley Mine
  2. Theba
  3. Painted Rock Mining District
  4. Painted Rock Mountains
  5. Maricopa County
  6. Arizona
  7. USA

33.0492°, -113.0330°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Light green-blue
Streak
White
Tenacity
brittle
Cleavage
Distinct/Good

Probably (100) and (001)

Fracture
Splintery
Density
2.12 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 58.5°
Refractive index
1.54 – 1.582
Surface relief
Moderate
Principal indices
nα 1.540 · nβ 1.550 · nγ 1.582
Pleochroism
Visible

X = pale blue, Y = nearly colorless, Z = lightblue; Y<X<Z

Dispersion
moderate, r>v
Notes

Z=b,Y≈a

Michel-Lévy diagramhighlighted lineδ = 0.0420
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]420 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation420 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 10.356(6) Å · b = 8.923(5) Å · c = 13.486(7) Å
Cell angles
β = 92.618(9) °
Ratio a:b:c
1 : 0.862 : 1.302
Unit cell volume
1244.9 ų
Z
2
Type-locality form

Needles or narrow blades up to about 0.2 mm in length

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2515.999399.975
53.25%
15PPhosphorusPhosphorus430.974123.896
16.50%
23VVanadiumVanadium250.942101.884
13.57%
7NNitrogenNitrogen514.00770.035
9.32%
1HHydrogenHydrogen311.00831.248
4.16%
6CCarbonCarbon212.01124.022
3.20%
Total751.060100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Davidbrowniet-(NH4)
  • Davidbrownite
  • IMA2018-129

In other languages

German
Davidbrownit-(NH4) · IMA 2018-129

Classification

Strunz
10th ed.

8.DG

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DGWith large and medium-sized cations, (OH, etc.):RO4< 0.5:1Group
  • 8.DGDavidbrownite-(NH4)Species

Literature, links & citation

Citations
  1. 2019Miyawaki, Ritsuro, Hålenius, Ulf, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2019) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) NEWSLETTER 47. European Journal of Mineralogy, 31 (1) 197-202 doi:10.1127/ejm/2019/0031-2839DOI: 10.1127/ejm/2019/0031-2839
  2. 2019Kampf, Anthony R., Cooper, Mark A., Rossman, George R., Nash, Barbara P., Hawthorne, Frank. C., Marty, Joe (2019) Davidbrownite-(NH4), (NH4,K)5(V4+O)2(C2O4)[PO2.75(OH)1.25]4·3H2O, a new phosphate–oxalate mineral from the Rowley mine, Arizona, USA. Mineralogical Magazine, 83 (6) 869-877 doi:10.1180/mgm.2019.56DOI: 10.1180/mgm.2019.56
  3. 2022(2022) Davidbrownite-(NH4). Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Davidbrownite-(NH4) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/davidbrownite-nh4-53370},
  note      = {Accessed 2026-05-11}
}