Defernite

Ca6(CO3)1.58(Si2O7)0.21(OH)7[Cl0.50(OH)0.08(H2O)0.42]
IMA status
  • Approved
IMA symbol
Def
Discovered
1978
IMA approved
1978
Also known as
  • Deferniet
  • IMA1978-057

Where it forms, where it's found

Geological setting

Secondary alteration product of high-temperature calc-silicates. In skarn produced by a granitic intrusion into limestone.

Primary, glassy subhedral grains intergrown primarily with hausmannite.

Type locality
Güneyce-Ikizdere
  1. Rize Province
  2. Turkey
1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
Colourless (original occurrence) · also deep red · rose-brown

Red to rose brown colors probably due to Mn.

Streak
Colorless, also Pink
Tenacity
brittle
Cleavage
Perfect

perfect (010) and distinct (100)

Fracture
Splintery · Conchoidal
Density
2.34 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 42° · 2V calc = 42°
Refractive index
1.546 – 1.576
Surface relief
Moderate
Principal indices
nα 1.546 · nβ 1.572 · nγ 1.576
Birefringence
0.030
Pleochroism
Strong

X = ochre-brown, Y= brownish-orange to ochre-brown, Z= colorless to yellow

Dispersion
medium r < v (Turkey)
Extinction
Parallel. X = c, Y = b
Michel-Lévy diagramhighlighted lineδ = 0.0300
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]300 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation300 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#71
Cell parameters
a = 17.860 Å · b = 22.775 Å · c = 3.658 Å
Ratio a:b:c
1 : 1.275 : 0.205
Z
8
Morphology

idiomorphic "porphyroblastic" laths

Type-locality form

Small subiodiomorphic to idiomorphic crystals, 100-200 µm in length and fibro-radiating patches.

Comment

space group Pna2, or Pnam

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
20CaCalciumCalcium640.078240.468
46.58%
8OOxygenOxygen13.7115.999219.346
42.48%
6CCarbonCarbon1.5812.01118.977
3.68%
17ClChlorineChlorine0.535.45017.725
3.43%
14SiSiliconSilicon0.4228.08511.796
2.28%
1HHydrogenHydrogen7.921.0087.983
1.55%
Total516.296100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Mn
  • Mg

Synonyms

  • Deferniet
  • IMA1978-057

In other languages

German
Defernit · IMA 1978-057
Italian
Defernite
Chinese
戴碳钙石

Classification

Strunz
10th ed.

5.BA.25

  • 5CarbonatesClass
  • 5.BCarbonates with additional anions, without H2ODivision
  • 5.BAWith Cu, Co, Ni, Zn, Mg, MnGroup
  • 5.BA.25DeferniteSpecies
Dana
8th ed.

16b.04.02.01

  • 16bHydrated Carbonates Containing Hydroxyl or HalogenClass
  • 16b.04AmBn(XO3)pZqxH2O & with (m+n):p = 3:1Type
  • 16b.04.02— unnamed intermediate level —Group
  • 16b.04.02.01DeferniteSpecies
CIM

12.1.5

  • 12Carbonates with other anionsClass
  • 12.1Carbonates with halidesGroup
  • 12.1.5DeferniteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1980Sarp, Halil, Taner, Mehmet Fevzi, Deferne, Jacques, Bizouard, Hélène, Liebich, Bernard W. (1980) La defernite, Ca6(CO3)2(OH, Cl)8 •nH2O, un nouveau carbonate de calcium chloro-hydroxylé. Bulletin de Minéralogie, 103 (2) 185-189 doi:10.3406/bulmi.1980.7395DOI: 10.3406/bulmi.1980.7395
  2. 1980Fleischer, M., Cabri, L. J., Chao, G. Y., Pabst, A. (1980) New mineral names. American Mineralogist, 65 (9-10). 1065-1070
  3. 1985Liebich, B.W., Sarp, H. (1985) La structure cristalline de la defernite. Schweizerische Mineralogische und Petrographische Mitteilungen, 65, 153-158. (in French)
  4. 1988Peacor, Donald R., Sarp, Halil, Dunn, Pete J., Innes, John, Nelen, Joseph A. (1988) Defernite from the Kombat mine, Namibia: A second occurrence, structure refinement, and crystal chemistry. American Mineralogist, 73 (7-8) 888-893
  5. 1991Dunn, Pete J. (1991) Rare Minerals of the Kombat Mine. The Mineralogical Record, 22 (6) 421-425
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Defernite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/defernite-1246},
  note      = {Accessed 2026-05-11}
}