Demartinite

K2SiF6
IMA status
  • Approved
IMA symbol
Dma
IMA approved
2006
Also known as
  • Camermanite
  • Demartiniet
  • IMA2006-034

Where it forms, where it's found

Geological setting

From a fumarole, on a fragment of altered pyroclastic breccia.

Type locality
La Fossa crater
  1. Vulcano Island
  2. Lipari
  3. Eolie Islands (Aeolian Islands)
  4. Metropolitan City of Messina
  5. Sicily
  6. Italy

38.4034°, 14.9614°

2recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
Colorless
Streak
White
Density
2.85 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.34 – 1.35
Surface relief
Low
Principal indices
nω 1.350 · nε 1.340
Pleochroism
Non-pleochroic
Michel-Lévy diagramhighlighted lineδ = 0.0100
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]100 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation100 nm
Order1st order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
#114
Cell parameters
a = 5.6461(8) Å · c = 9.2322(18) Å
Z
2
Morphology

Hexagonal pyramidal crystals. The observed forms are the pedion (001) and the hexagonal pyramid (112).

Type-locality form

Colorless hexagonal pyramidal crystals up to 0.3 mm across.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
9FFluorineFluorine618.998113.988
51.75%
19KPotassiumPotassium239.09878.196
35.50%
14SiSiliconSilicon128.08528.085
12.75%
Total220.269100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Camermanite
  • Demartiniet
  • IMA2006-034

In other languages

German
Demartinit · IMA 2006-034
Italian
demartinite

Classification

Strunz
10th ed.

3.CH.20

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.CHSilicofluoridesGroup
  • 3.CH.20DemartiniteSpecies
Dana
8th ed.

11.05.02.03

  • 11Halide ComplexesClass
  • 11.05AmBX6Type
  • 11.05.02Malladrite GroupGroup
  • 11.05.02.03DemartiniteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1952Denaeyer, Marcel E., Ledent, D. (1952) Sur la présence de la modification hexagonale de la hiératite (camermanite) dans des incrustations de sels potassiques d'une cheminée d'usine. Bulletin de Minéralogie, 75 (4) 231-236 doi:10.3406/bulmi.1952.4772DOI: 10.3406/bulmi.1952.4772
  2. 2007Gramaccioli, C. M., Campostrini, I. (2007) Demartinite, a new polymorph of K2SiF6 from La Fossa Crater, Vulcano, Aeolian Islands, Italy. The Canadian Mineralogist, 45 (5) 1275-1280 doi:10.2113/gscanmin.45.5.1275 DOI: 10.2113/gscanmin.45.5.1275
  3. 2022(2022) Demartinite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Demartinite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/demartinite-30908},
  note      = {Accessed 2026-05-11}
}