Dinilawiite

[Pb4OAl(OH)6]2(S2O3)2·(S2O3)(H2O)5
IMA status
  • Approved
IMA symbol
Dlw
IMA approved
2023
Also known as
  • Dinilawiiet

Where it forms, where it's found

Geological setting

Weathered galena-sphalerite-chalcopyrite-quartz vein

Type locality
Redmond Mine
  1. Waterville Lake
  2. Haywood County
  3. North Carolina
  4. USA

35.6802°, -83.0186°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
colorless

sometimes appears light reddish brown due to inclusions or transmitted color of the matrix

Streak
white
Tenacity
brittle
Cleavage
None Observed

curved

Fracture
Conchoidal
Density
4.727 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 78°
Refractive index
1.805 – 1.854
Surface relief
Very high
Principal indices
nα 1.805 · nβ 1.824 · nγ 1.854
Pleochroism
Non-pleochroic
Dispersion
moderate r > v dispersion
Notes

β = 1.824 (calc), γ = 1.854 (calc)

Michel-Lévy diagramhighlighted lineδ = 0.0490
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]490 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation490 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 17.4100(5) Å · b = 9.2191(2) Å · c = 21.698(1) Å
Cell angles
β = 107.276(8) °
Ratio a:b:c
1 : 0.530 : 1.246
Z
4
Twinning

By reflection on (001) and 180° rotation on [100].

Type-locality form

ubiquitously twinned tablets, up to about 0.4 mm across, with angled striations. Crystals always occur in tightly intergrown subparallel clusters.

Comment

the space group is I2/a

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead8207.2001657.600
69.82%
8OOxygenOxygen2815.999447.972
18.87%
16SSulfurSulfur632.060192.360
8.10%
13AlAluminiumAluminium226.98253.964
2.27%
1HHydrogenHydrogen221.00822.176
0.94%
Total2374.072100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From Mindat formula

Synonyms

  • Dinilawiiet

In other languages

German
Dinilawiit

Classification

Strunz
10th ed.

7.JA

  • 7SulfatesClass
  • 7.JThiosulfatesDivision
  • 7.JAThiosulfates of PbGroup
  • 7.JADinilawiiteSpecies

Literature, links & citation

Citations
  1. 2023Bosi, Ferdinando, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2023) Newsletter 76. Mineralogical Magazine, 1-5 doi:10.1180/mgm.2023.89 DOI: 10.1180/mgm.2023.89
  2. 2024Kampf, Anthony R.; Smith, Jason B.; Hughes, John M.; Ma, Chi; Emproto, Christopher (2024) New Minerals from the Redmond Mine, North Carolina, USA: VIII. Dinilawiite, a Thiosulfate Mineral with an Open Framework Structure. The Canadian Journal of Mineralogy and Petrology, 62 (6). 871-879 doi:10.3749/2400016DOI: 10.3749/2400016
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Dinilawiite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/dinilawiite-470931},
  note      = {Accessed 2026-05-11}
}