Dioptase

CuSiO3 · H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Dpt
Discovered
1797
Also known as

History

Late in the 18th century, copper miners at the Altyn-Tyube mine in what is now Kazakhstan thought they had found emerald. The crystals were a striking transparent green — the exact colour and clarity a Russian buyer would expect from emerald. Specimens were dispatched to Moscow for analysis.

The verdict came back unflattering. The green stone had a Mohs hardness — its resistance to scratching — of only about 5, soft enough to mark with a steel knife. Emerald sits much higher at 8. That difference alone ruled out emerald. In 1797, the French mineralogist René Just Haüy concluded the Altyn-Tyube material was an unknown species and named it dioptase.

The name comes from the Greek dia — through — and a verb meaning to see. It points to the crystal's clearest peculiarity. Its cleavage planes — the flat surfaces along which it would split if struck — are visible through the transparent body of an unbroken specimen. The viewer can see, from the outside, where the stone would prefer to break.

Industrial & practical applications

Dioptase has no industrial role. It is a copper-bearing mineral, but it occurs in quantities far too small, and in deposits far too scattered, to interest any copper smelter. What demand exists is from collectors.

Among mineral collectors, dioptase is prized for the deep emerald-green of its crystals. The Tsumeb mine in Namibia has long been considered the source of the finest specimens. The original locality at Altyn-Tyube in Kazakhstan, several sites in Arizona, and deposits in the Republic of the Congo also feed the cabinet trade.

The mineral is occasionally cut into small emerald-like gems, but two properties hold it back from any serious place in jewellery. Its Mohs hardness of 5 — about the hardness of tooth enamel — means it scratches easily in everyday wear. Its perfect cleavage — the tendency to split along flat internal planes — runs in three directions, so a sharp knock can break the stone open. Faceted dioptase is therefore a specialist gem, kept for display rather than rings.

A more curious use is as a green pigment: pulverised crystals yield an intense colour. The powder is toxic because of its copper content, and accidental ingestion can cause serious harm. The toxicity has kept the pigment use marginal.

Where it forms, where it's found

Geological setting

A secondary mineral in the oxidized zones of copper deposits.

In the oxidized zone of some copper deposits.

Type locality
Altyn-Tyube dioptase deposit (Altyn-Tube)
  1. Altyn-Tyube area
  2. Bukhar-Zhyrau District
  3. Karaganda Region
  4. Kazakhstan

49.8164°, 73.9950°

154recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Emerald Green · blue-green
Streak
Green
Tenacity
brittle
Cleavage
Perfect

Perfect on (1011)

Fracture
Irregular/Uneven · Conchoidal
Density
3.28 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.652 – 1.71
Surface relief
High
Principal indices
nω 1.652 – 1.658 · nε 1.704 – 1.71
Pleochroism
Weak

absorption reported as O>E; however, absorption observed as O = very pale powder blue, E = pale cyan; E>O

UV response
Nonfluorescent in UV.
Michel-Lévy diagramhighlighted lineδ = 0.0520
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]520 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation520 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#80
Cell parameters
a = 14.566 Å · c = 7.778 Å
Z
18
Morphology

Long to short prismatic [0001], dominant forms (1120), and (0221), (1341).

Twinning

On (1011), uncommon.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
40.59%
29CuCopperCopper163.54663.546
40.31%
14SiSiliconSilicon128.08528.085
17.82%
1HHydrogenHydrogen21.0082.016
1.28%
Total157.643100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Achirit
  • Achirita
  • Achirite
  • Achrit
  • Achrita
  • Achrite
  • Aschirit
  • Aschirita
  • Aschirite
  • Ashirite
  • Dioptasit
  • Dioptasita
  • Dioptasite
  • Emerald-copper
  • Emerald-malachite
  • Emeraudine
  • Kirghisit
  • Kirghisita
  • Kirghisite
  • Kupfer-Smaragd
  • Kupfergrün crystallisirtes
  • Rhombohedral Emerald Malachite
  • Smaragdo-chalcite (of Mohs)

In other languages

French
achirite · achrite · aschirite · CuSiO3,H2O · dioptase · dioptasite · kirghisite · rhombohedral emerald malachite · smaragdo-chalcite
German
Dioptas · Kieselkupfersmaragd · Kupfersmaragd
Spanish
Dioptasa
Italian
dioptasio
Japanese
翠銅鉱
Chinese
綠銅礦 · 青銅礦
Simplified Chinese
青铜矿
Traditional Chinese
青銅礦
Russian
диоптаз · киргизит · медный изумруд · пхирит · пширит
Arabic
دیوبتاز

Classification

Strunz
10th ed.

9.CJ.30

  • 9SilicatesClass
  • 9.CCyclosilicatesDivision
  • 9.CJ[Si6O18]12- 6-membered single rings (sechser-Einfachringe), without insular complex anionsGroup
  • 9.CJ.30DioptaseSpecies
Dana
8th ed.

61.01.03.01

  • 61Cyclosilicates Six-membered RingsClass
  • 61.01Six-Membered Rings with [Si6O18] rings; possible (OH) and Al substitutionType
  • 61.01.03— unnamed intermediate level —Group
  • 61.01.03.01DioptaseSpecies
CIM

14.2.1

  • 14Silicates not Containing AluminumClass
  • 14.2Silicates of CuGroup
  • 14.2.1DioptaseSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. Traite de Minéralogie: III: 477.
  2. Soviet Physics – Doklady: 23: 215-217.
  3. 1793Delamétherie, J.C. (1793) De la cristallisation d'une émeraude. Observations sur la Physique, sur l’Histoire Naturelle et sur les Arts: 42: 154-154.
  4. 1796Haüy, René Just (1796) Extrait du Traité Élémentaire de Minéralogie que le C.en Haüy s'occupe de rédiger. Journal des mines, 5 (28). 249-334
  5. 1798Haüy, C. (1798) Sur la dioptase. Bulletin des Science, par la Société Philomathique: 1798: 101-101.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Dioptase — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/dioptase-1295},
  note      = {Accessed 2026-05-11}
}