Dioskouriite

CaCu4Cl6(OH)4 · 4H2O
IMA status
  • Approved
IMA symbol
Dio
Discovered
2014
IMA approved
2016
Also known as
  • Dioskouriiet
  • IMA2015-106

Where it forms, where it's found

Geological setting

Fumarolic. Possibly formed through interactions involving high-temperature sublimate minerals, fumarolic gas and atmospheric water vapor at temperatures not higher than 150 C.

Type locality
Arsenatnaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.6833°, 160.2333°

2recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
Bright green · Grey
Tenacity
brittle
Cleavage
Distinct/Good

One distinct (believed to be (100)) and one imperfect

Fracture
Irregular/Uneven
Density
2.75 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 70° · 2V calc = 75.5°
Refractive index
1.695 – 1.75
Surface relief
High
Principal indices
nα 1.695 · nβ 1.715 · nγ 1.750
Pleochroism
Strong

Z (grass green) > Y (yellowish-green) > X (pale yellowish-green)

Dispersion
very strong, r < v
Michel-Lévy diagramhighlighted lineδ = 0.0550
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]550 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation550 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 7.2792(8) Å · b = 10.3000(7) Å · c = 20.758(2) Å
Cell angles
β = 100.24(1) °
Ratio a:b:c
1 : 1.415 : 2.852
Unit cell volume
1531.6 ų
Z
4
Morphology

Tabbular to lamellar, sometimes pseudohexagonal, or flattened prismatic, with domatic terminations that are typically sword-like.

Type-locality form

Green sword-like crystals in groups or crusts up to 1 × 2 mm2

Comment

For dioskouriite-2O, a=7.3193(7), b=10.3710(10), c=20.560(3)

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper463.546254.184
39.28%
17ClChlorineChlorine635.450212.700
32.87%
8OOxygenOxygen815.999127.992
19.78%
20CaCalciumCalcium140.07840.078
6.20%
1HHydrogenHydrogen121.00812.096
1.87%
Total647.050100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Dioskouriiet
  • IMA2015-106

In other languages

German
Dioskouriit · IMA 2015-106

Classification

Strunz
10th ed.

3.DA.70

  • 3HalidesClass
  • 3.DOxyhalides, hydroxyhalides and related double halidesDivision
  • 3.DAWith Cu, etc., without PbGroup
  • 3.DA.70DioskouriiteSpecies

Literature, links & citation

Citations
  1. 2016(2016)
  2. 2016(2016)
  3. 2016Hålenius, U., Hatert, F., Pasero, M., Mills, S.J. (2016) New minerals and nomenclature modifications approved in 2016, CNMNC Newsletter no 30. Mineralogical Magazine, 80 (2) 407-413 doi:10.1180/minmag.2016.080.081DOI: 10.1180/minmag.2016.080.081
  4. 2021Pekov, Igor V., Zubkova, Natalia V., Zolotarev, Andrey A., Yapaskurt, Vasiliy O., Krivovichev, Sergey V., Belakovskiy, Dmitry I., Lykova, Inna, Vigasina, Marina F., Kasatkin, Anatoly V., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2021) Dioskouriite, CaCu4Cl6(OH)4·4H2O: A New Mineral Description, Crystal Chemistry and Polytypism. Minerals, 11 (1) 90 doi:10.3390/min11010090 DOI: 10.3390/min11010090
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Dioskouriite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/dioskouriite-47598},
  note      = {Accessed 2026-05-11}
}