Where it forms, where it's found
- Geological setting
Fumarole, about 200°C
- Type locality
- Second scoria cone
- Northern Breakthrough (North Breach)
- Great Fissure eruption (Main Fracture)
- Tolbachik Volcanic field
- Milkovsky District
- Kamchatka Krai
- Russia
55.6878°, 160.2435°
1recorded occurrences
Physical
Optical
- Optical type
- Uniaxial (+)
- Refractive index
- 1.489 – 1.491
- Principal indices
- nω 1.489 · nε 1.491
- Pleochroism
- Not Visible
- Dispersion
- None observed
Δ = 0Δmax
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation20 nm
Order1st order
XPL colour
Crystallography
- Space group
- #78
- Cell parameters
- a = 15.7223(2) Å · c = 22.0160(5) Å
- Unit cell volume
- 4713.1 ų
- Z
- 18
- Parting
- None observed
- Type-locality form
Aggregates of tabular crystals up to 1-2 mm in maximum dimension, with abundant gas inclusions.
Crystal structure
Chemical composition
Synonyms
- Dobrovolskyiet
In other languages
- German
- Dobrovolskyit · IMA 2019-106
Classification
Strunz
10th ed.7.AD
- 7SulfatesClass
- 7.ASulfates (selenates, etc.) without additional anions, without H2ODivision
- 7.ADWith only large cationsGroup
- 7.ADDobrovolskyiteSpecies
Literature, links & citation
Citations
- 2020Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2020) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) - Newsletter 54. European Journal of Mineralogy, 32 (2) 275-283 doi:10.5194/ejm-32-275-2020 DOI: 10.5194/ejm-32-275-2020
- 2021Shablinskii, Andrey P., Filatov, Stanislav K., Krivovichev, Sergey V., Vergasova, Lidiya P., Moskaleva, Svetlana V., Avdontseva, Eugeniya Yu., Knyazev, Alexander V., Bubnova, Rimma S. (2021) Dobrovolskyite, Na4Ca(SO4)3, a new fumarolic sulfate from the Great Tolbachik fissure eruption, Kamchatka Peninsula, Russia. Mineralogical Magazine, 85 (2) 233-241 doi:10.1180/mgm.2021.9DOI: 10.1180/mgm.2021.9
- 2023Shablinskii, Andrey P., Filatov, Stanislav K., Biryukov, Yaroslav P. (2023) Crystal structures inherited from parent high-temperature disordered microblocks: Ca2SiO4, Na2SO4–K2SO4 sulfates, and related minerals (bubnovaite and dobrovolskyite) Physics and Chemistry of Minerals, 50 (4) 30 doi:10.1007/s00269-023-01253-6DOI: 10.1007/s00269-023-01253-6
Cite this entry
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Dobrovolskyite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/dobrovolskyite-54346},
note = {Accessed 2026-05-11}
}