Dobrovolskyite

Na4Ca(SO4)3
IMA status
  • Approved
IMA symbol
Dvo
Discovered
2000
Also known as
  • Dobrovolskyiet

Where it forms, where it's found

Geological setting

Fumarole, about 200°C

Type locality
Second scoria cone
  1. Northern Breakthrough (North Breach)
  2. Great Fissure eruption (Main Fracture)
  3. Tolbachik Volcanic field
  4. Milkovsky District
  5. Kamchatka Krai
  6. Russia

55.6878°, 160.2435°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Streak
White
Fracture
Conchoidal
Density
2.68 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.489 – 1.491
Surface relief
Low
Principal indices
nω 1.489 · nε 1.491
Pleochroism
Not Visible
Dispersion
None observed
Michel-Lévy diagramhighlighted lineδ = 0.0020
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]20 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation20 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#78
Cell parameters
a = 15.7223(2) Å · c = 22.0160(5) Å
Unit cell volume
4713.1 ų
Z
18
Parting
None observed
Type-locality form

Aggregates of tabular crystals up to 1-2 mm in maximum dimension, with abundant gas inclusions.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
45.69%
16SSulfurSulfur332.06096.180
22.89%
11NaSodiumSodium422.99091.960
21.88%
20CaCalciumCalcium140.07840.078
9.54%
Total420.206100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Dobrovolskyiet

In other languages

German
Dobrovolskyit · IMA 2019-106

Classification

Strunz
10th ed.

7.AD

  • 7SulfatesClass
  • 7.ASulfates (selenates, etc.) without additional anions, without H2ODivision
  • 7.ADWith only large cationsGroup
  • 7.ADDobrovolskyiteSpecies

Literature, links & citation

Citations
  1. 2020Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2020) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) - Newsletter 54. European Journal of Mineralogy, 32 (2) 275-283 doi:10.5194/ejm-32-275-2020 DOI: 10.5194/ejm-32-275-2020
  2. 2021Shablinskii, Andrey P., Filatov, Stanislav K., Krivovichev, Sergey V., Vergasova, Lidiya P., Moskaleva, Svetlana V., Avdontseva, Eugeniya Yu., Knyazev, Alexander V., Bubnova, Rimma S. (2021) Dobrovolskyite, Na4Ca(SO4)3, a new fumarolic sulfate from the Great Tolbachik fissure eruption, Kamchatka Peninsula, Russia. Mineralogical Magazine, 85 (2) 233-241 doi:10.1180/mgm.2021.9DOI: 10.1180/mgm.2021.9
  3. 2023Shablinskii, Andrey P., Filatov, Stanislav K., Biryukov, Yaroslav P. (2023) Crystal structures inherited from parent high-temperature disordered microblocks: Ca2SiO4, Na2SO4–K2SO4 sulfates, and related minerals (bubnovaite and dobrovolskyite) Physics and Chemistry of Minerals, 50 (4) 30 doi:10.1007/s00269-023-01253-6DOI: 10.1007/s00269-023-01253-6
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Dobrovolskyite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/dobrovolskyite-54346},
  note      = {Accessed 2026-05-11}
}