Dokuchaevite

Cu8O2(VO4)3Cl3
IMA status
  • Approved
IMA symbol
Dok
IMA approved
2018
Also known as
  • Dokuchaeviet
  • IMA2018-012

Where it forms, where it's found

Geological setting

Fumarole.

Type locality
Yadovitaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.8333°, 160.3333°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
dark red
Streak
reddish black
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
4.142 g/cm³

Optical

Pleochroism
Non-pleochroic
Optical colour
grey with yellowish tint
Anisotropism
ΔR589 = 0.85%
Bireflectance
weak
Internal reflections
yellow-red internal reflections
Tropism
Anisotropic
Reflectance R%
(12.15,11.07) 400, (12.62,11.55) 420, (12.97,11.92) 440, (13.20,12.22) 460, (13.30,12.36) 470, (13.40,12.50) 480, (13.55,12.67) 500, (13.69,12.82) 520, (13.79,12.94) 540, (13.81,12.96) 546, (13.84,13.01) 560, (13.88,13.03) 580, (13.87,13.02) 589, (13.86,13.01) 600, (13.83,12.96) 620, (13.79,12.88) 640, (13.75,12.84) 650, (13.71,12.79) 660, (13.57,12.65) 680, (13.44,12.47) 700
Reflected-light panel
13.5 %anisotropic · dual curve
Specimen sRGB 140, 96, 49
White reference100 % reflector under same lamp
R₁ R₂
Mode
Bireflectance
weak
Anisotropism
ΔR589 = 0.85%
Reflected colour
grey with yellowish tint
Internal reflections
yellow-red internal reflections

Crystallography

Crystal system
Triclinic
Space group
P-1
Cell parameters
a = 6.332(3) Å · b = 8.204(4) Å · c = 15.562(8) Å
Cell angles
α = 90.498(8) ° · β = 91.173(7) ° · γ = 90.896(13) °
Ratio a:b:c
1 : 1.296 : 2.458
Unit cell volume
801.9 ų
Z
2
Parting
none
Type-locality form

Individual prismatic crystals growing on crusts of various Cu sulphate exhalative minerals.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper863.546508.368
51.27%
8OOxygenOxygen1415.999223.986
22.59%
23VVanadiumVanadium350.942152.826
15.41%
17ClChlorineChlorine335.450106.350
10.73%
Total991.530100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Dokuchaeviet
  • IMA2018-012

In other languages

German
Dokuchaevit · IMA 2018-012

Classification

Strunz
10th ed.

8.BB.45

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BBWith only medium-sized cations, (OH, etc.):RO4 about 1:1Group
  • 8.BB.45DokuchaeviteSpecies

Literature, links & citation

Citations
  1. 1949Sumin, N.G. (1949) Trudy Mineralogicheskogo Muzeya AN SSSR: 1: 93. (in Russian)
  2. 2018Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2018) CNMNC Newsletter No 43, New minerals and nomenclature modifications approved in 2018. Mineralogical Magazine, 82 (3) 779-785 doi:10.1180/mgm.2018.72DOI: 10.1180/mgm.2018.72
  3. 2019Siidra, Oleg I., Nazarchuk, Evgeny V., Zaitsev, Anatoly N., Polekhovsky, Yury S., Wenzel, Thomas, Spratt, John (2019) Dokuchaevite, Cu8O2(VO4)3Cl3, a new mineral with remarkably diverse Cu2+ mixed-ligand coordination environments. Mineralogical Magazine, 83 (5) 749-755 doi:10.1180/mgm.2019.41 DOI: 10.1180/mgm.2019.41
  4. 2022(2022) Dokuchaevite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Dokuchaevite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/dokuchaevite-52762},
  note      = {Accessed 2026-05-11}
}