Dolerophanite

Cu2O(SO4)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Dph
Discovered
1873
Also known as
  • Dolerophan
  • Dolerophane
  • Dolerophaniet
  • +2 more

Where it forms, where it's found

Geological setting

Active volcanic fumaroles.

Active volcanic fumaroles.

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
9recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent · Opaque
Colour
Dark brown · nearly black · yellow-brown in transmitted light.
Streak
Yellowish-brown
Cleavage
Perfect

On (101), perfect.

Density
4.17 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 85° · 2V calc = 70°
Refractive index
1.715 – 1.88
Surface relief
High
Principal indices
nα 1.715 · nβ 1.820 · nγ 1.880
Pleochroism
Visible

X = Dark brown; Y = Brownish yellow; Z = Lemon-yellow.

Dispersion
r < v
Extinction
Y = b; Z ∧ c = –10°.
Michel-Lévy diagramhighlighted lineδ = 0.1650
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1650 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1650 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 9.370(2) Å · b = 6.319(2) Å · c = 7.639(1) Å
Cell angles
β = 122.34(1) °
Ratio a:b:c
1 : 0.674 : 0.815
Z
4
Morphology

Crystals commonly elongated [010], and more or less tabular on (101); small. Faces in the zone [010] commonly striated [010]; other faces smooth and lustrous.

Type-locality form

As a sublimate.

Comment

synthetic

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper263.546127.092
53.14%
8OOxygenOxygen515.99979.995
33.45%
16SSulfurSulfur132.06032.060
13.41%
Total239.147100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Dolerophan
  • Dolerophane
  • Dolerophaniet
  • Dolerophanita
  • Dolerophano

In other languages

German
Dolerophanit
Italian
Dolerofanite

Classification

Strunz
10th ed.

7.BB.20

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BBWith medium-sized cationsGroup
  • 7.BB.20DolerophaniteSpecies
Dana
8th ed.

30.02.02.01

  • 30Anhydrous Sulfates Containing Hydroxyl or HalogenClass
  • 30.02(AB)2(XO4)ZqType
  • 30.02.02— unnamed intermediate level —Group
  • 30.02.02.01DolerophaniteSpecies
CIM

25.2.5

  • 25SulphatesClass
  • 25.2Sulphates of Cu and AgGroup
  • 25.2.5DolerophaniteSpecies

Literature, links & citation

Citations
  1. 1873Scacchi, A. (1873) Nuove specie di solfati di rame (Dolerofano). Note Mineralogiche, Memoria Prima, Napoli, Stamperia del Fibreno: 22-29.
  2. 1886Goldschmidt, Victor (1886) Index der Krystallformen der Mineralien Vol. 1. Springer Berlin Heidelberg. doi:10.1007/978-3-662-28591-6 DOI: 10.1007/978-3-662-28591-6
  3. 1902Strandmark (1902) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 36: 457.
  4. 1935Zambonini, Ferruccio (1935) Mineralogia Vesuviana. second edition with Quercigh, 463 pp., Naples: 161.
  5. 1940Richmond, Wallace E. (1940) Crystal chemistry of the phosphates, arsenates and vanadates of the type A2XO4(Z). American Mineralogist, 25 (7). 441-479
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Dolerophanite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/dolerophanite-1302},
  note      = {Accessed 2026-05-11}
}