Donowensite

Ca(H2O)3Fe3+2(V2O7)2
IMA status
  • Approved
IMA symbol
Dnw
IMA approved
2020
Also known as
  • Donowensiet
  • IMA2020-067

Where it forms, where it's found

Geological setting

Oxidation of primary ore V minerals contained in altered rocks contacting with an igneous complex.

Type locality
North Wilson pit
  1. Union Carbide Mine
  2. Wilson Springs (Potash Sulfur Springs)
  3. Garland County
  4. Arkansas
  5. USA

34.4778°, -92.9681°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Yellow
Streak
Orange
Tenacity
brittle
Cleavage
Perfect

on (001); also very good on (100) and (010)

Fracture
Splintery
Density
2.97 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 72°
Pleochroism
Visible

X = brown orange; Y = orange yellow; Z = yellow.

Dispersion
r > v, moderate
Extinction
X ∧ b = 7°; Z ≈ c.
Notes

nα > 1.95; nβ > 1.95; nγ > 1.95. The Gladstone-Dale relationship predicts an average R.I. of 1.958. Had the authors reported an observed birefringence, that combined with the 2V and predicted average R.I. could have allowe

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 7.3452(4) Å · b = 9.9291(4) Å · c = 10.0151(7) Å
Cell angles
α = 94.455(7) ° · β = 98.476(7) ° · γ = 100.779(7) °
Ratio a:b:c
1 : 1.352 : 1.363
Z
2
Type-locality form

Needles, up to 1 mm in length.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1715.999271.983
42.93%
23VVanadiumVanadium450.942203.768
32.16%
26FeIronIron255.845111.690
17.63%
20CaCalciumCalcium140.07840.078
6.33%
1HHydrogenHydrogen61.0086.048
0.95%
Total633.567100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Donowensiet
  • IMA2020-067

In other languages

German
Donowensit · IMA 2020-067

Classification

Strunz
10th ed.

8.FC

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.FPolyphosphates, Polyarsenates, [4]-PolyvanadatesDivision
  • 8.FCPolyphosphates, etc., with H2O onlyGroup
  • 8.FCDonowensiteSpecies

Literature, links & citation

Citations
  1. 2021Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2021) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 59. European Journal of Mineralogy, 33 (1) 139-143 doi:10.5194/ejm-33-139-2021 DOI: 10.5194/ejm-33-139-2021
  2. 2022Kampf, Anthony R., Hughes, John M., Nash, Barbara P., Smith, Jason B. (2022) Donowensite, Ca(H2O)3Fe3+2(V2O7)2, and mikehowardite, Fe3+4(VO4)4(H2O)2·H2O, two new vanadium minerals from the Wilson Springs Vanadium Mine, Wilson Springs, Arkansas, USA. The Canadian Mineralogist, 60 (3) 543-554 doi:10.3749/canmin.210015DOI: 10.3749/canmin.210015
  3. 2023(2023) Donowensite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Donowensite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/donowensite-55311},
  note      = {Accessed 2026-05-11}
}