Dorfmanite

Na2(PO3OH) · 2H2O
IMA status
  • Approved
IMA symbol
Dfm
Discovered
1979
IMA approved
1979
Also known as
  • Dorfmaniet
  • IMA1979-053

Where it forms, where it's found

Type locality
Koashva Open Pit
  1. Koashva Mt
  2. Murmansk Oblast
  3. Russia

67.6167°, 34.0000°

11recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101 – 1.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
White
Density
1.98 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 65° · 2V calc = 82°
Refractive index
1.454 – 1.471
Surface relief
Low
Principal indices
nα 1.454 · nβ 1.461 · nγ 1.471
Dispersion
very weak
Michel-Lévy diagramhighlighted lineδ = 0.0170
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]170 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation170 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#61
Cell parameters
a = 10.34 Å · b = 16.82 Å · c = 6.601 Å
Ratio a:b:c
1 : 1.627 : 0.638
Z
8
Type-locality form

Powdery aggregates and incrustations, with individual particles up to 15 µm.

Comment

Space group from synthetic material (Catti et al., 1977).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen615.99995.994
53.93%
11NaSodiumSodium222.99045.980
25.84%
15PPhosphorusPhosphorus130.97430.974
17.40%
1HHydrogenHydrogen51.0085.040
2.83%
Total177.988100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Dorfmaniet
  • IMA1979-053

In other languages

German
Dorfmanit · IMA 1979-053
Italian
Dorfmanite
Chinese
水磷氢钠石
Russian
Дорфманит

Classification

Strunz
10th ed.

8.CJ.60

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CJWith only large cationsGroup
  • 8.CJ.60DorfmaniteSpecies
Dana
8th ed.

39.01.08.01

  • 39Hydrated Acid Phosphates, Arsenates and VanadatesClass
  • 39.01A[HXO4]·xH2OType
  • 39.01.08— unnamed intermediate level —Group
  • 39.01.08.01DorfmaniteSpecies
CIM

19.1.4

  • 19PhosphatesClass
  • 19.1Phosphates of the alkali metalsGroup
  • 19.1.4DorfmaniteSpecies

Literature, links & citation

Citations
  1. 1977Catti, M., Ferraris, G., Franchini-Angela, M. (1977) The crystal structure of Na2HPO4.2H2O. Competition between coordination and hydrogen bonds. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 33 (11) 3449-3452 doi:10.1107/s0567740877011170DOI: 10.1107/s0567740877011170
  2. 1980Kapustin, Y.L., Pudovkina, Z.V., Bykova, T.E. (1980) Dorfmanite, a new mineral. Zapiski Vsesoyuznogo (Vserossiyskogo) Mineralogicheskogo Obshchestva: 109(2): 211-216. (in Russian)
  3. 1981Fleischer, Michael, Chao, George Y., Francis, Carl A., Pabst, and Adolf (1981) New Mineral Names. American Mineralogist, 66 (1-2) 217-220
  4. 1982Kapustin, Yu. L., Pudovkina, Z. V., Bykova, T. Ye. (1982) Dorfmanite, a new mineral. International Geology Review, 24 (1) 111-115 doi:10.1080/00206818209452379DOI: 10.1080/00206818209452379
  5. 1990Templeton, David H., Ruben, Helena W., Zalkin, Allan. (1990) Entropy and crystal structure of hydrates of disodium hydrogen phosphate. The Journal of Physical Chemistry, 94 (20). 7830-7834 doi:10.1021/j100383a017DOI: 10.1021/j100383a017
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Dorfmanite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/dorfmanite-1312},
  note      = {Accessed 2026-05-11}
}