Douglasite

K2Fe2+Cl4 · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Dgl
Discovered
1880
Also known as
  • Douglasiet
  • Eisenchlorürchlorkalium

Where it forms, where it's found

Type locality
Douglashall I-II potash mine
  1. Westeregeln
  2. Börde-Hakel
  3. Salzlandkreis
  4. Saxony-Anhalt
  5. Germany

51.9578°, 11.3844°

5recorded occurrences
Source · OpenStreetMap

Physical

Lustre
Vitreous
Transparency
Translucent
Colour
Light green · brownish red on exposure.
Density
2.16 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 5°
Refractive index
1.488 – 1.5
Surface relief
Low
Principal indices
nα 1.488 · nβ 1.488 · nγ 1.5
Michel-Lévy diagramhighlighted lineδ = 0.0120
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]120 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation120 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 11.80 Å · b = 16.27 Å · c = 8.225 Å
Cell angles
β = 104.89 °
Ratio a:b:c
1 : 1.379 : 0.697
Unit cell volume
1526 ų
Z
6
Morphology

Coarsely granular masses.

Type-locality form

Coarsely granular masses.

Comment

Space Group: n.d.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
17ClChlorineChlorine435.450141.800
45.47%
19KPotassiumPotassium239.09878.196
25.07%
26FeIronIron155.84555.845
17.91%
8OOxygenOxygen215.99931.998
10.26%
1HHydrogenHydrogen41.0084.032
1.29%
Total311.871100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Douglasiet
  • Eisenchlorürchlorkalium

In other languages

French
douglasite
German
Douglasit
Spanish
Douglasita
Italian
Douglasite

Classification

Strunz
10th ed.

3.CJ.20

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.CJWith MX6 complexes; M = Fe, Mn, CuGroup
  • 3.CJ.20DouglasiteSpecies
Dana
8th ed.

11.03.01.01

  • 11Halide ComplexesClass
  • 11.03AmBX4·xH2OType
  • 11.03.01— unnamed intermediate level —Group
  • 11.03.01.01DouglasiteSpecies
CIM

8.11.4

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.11Halides of Fe and NiGroup
  • 8.11.4DouglasiteSpecies

Literature, links & citation

Citations
  1. 1877Ochsenius, C. (1877) Die Bildung der Steinsalzlager und ihrer Mutterlaugensalze [The formation of rock salt deposits and their mother liquor salts] - unter specieller Berücksichtigung der Flöze von Douglashall in der Egeln´schen Mulde [with special consideration of the Douglashall seams in the Egeln'sche Mulde]. Pfeffer, Halle.
  2. 1880Precht, H. (1880) Ueber die Bildung des Wasserstoffs in den Stassfurter Kalisalzbergwerken. Berichte der deutschen chemischen Gesellschaft, 13 (2) 2326-2328 doi:10.1002/cber.188001302262DOI: 10.1002/cber.188001302262
  3. 1909Boeke (1909) Neues Jahrbuch für Mineralogie, Geologie und Paleontologie, Heidelberg, Stuttgart: II: 44.
  4. 1921Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 DOI: 10.3133/b679
  5. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Douglasite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/douglasite-1314},
  note      = {Accessed 2026-05-11}
}