Dukeite

Bi3+24Cr6+8O57(OH)6 · 3H2O
IMA status
  • Approved
IMA symbol
Duk
IMA approved
1999
Also known as
  • Dukeiet
  • IMA1999-021

Where it forms, where it's found

Type locality
Posse mine
  1. São José de Brejaúba
  2. Conceição do Mato Dentro
  3. Minas Gerais
  4. Brazil
1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Resinous
Transparency
Transparent
Colour
Yellow to dirty yellow-brown
Streak
Bright yellow
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
7.171 g/cm³

Optical

Optical type
Uniaxial
Refractive index
2.33 – 2.37
Surface relief
Very high
Principal indices
nα 2.33 · nβ 2.37
Optical colour
Gray to purplish gray
Bireflectance
Very weak
Internal reflections
Yellow (strong)
UV response
none

Crystallography

Crystal system
Trigonal
Space group
#81
Cell parameters
a = 15.067(3) Å · c = 15.293(4) Å
Unit cell volume
3007 ų
Z
2
Morphology

Very tightly bound sheaves of parallel growth acicular crystals.

Twinning

None observed.

Type-locality form

Grouped sheaves / acicular crystals, possibly pseudomorphous after unnamed phase; aggregates are 1 x 0.3 mm2, and individuals up to 100 x 1-2 µm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
83BiBismuthBismuth24208.9805015.520
77.17%
8OOxygenOxygen6615.9991055.934
16.25%
24CrChromiumChromium851.996415.968
6.40%
1HHydrogenHydrogen121.00812.096
0.18%
Total6499.518100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • V

Synonyms

  • Dukeiet
  • IMA1999-021

In other languages

German
Dukeit · IMA 1999-021
Italian
Dukeite

Classification

Strunz
10th ed.

7.DF.80

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DFWith large and medium-sized cationsGroup
  • 7.DF.80DukeiteSpecies

Literature, links & citation

Citations
  1. 2000Burns, Peter C., Roberts, Andrew C., Stirling, John A.R., Criddle, Alan J., Feinglos, Mark N. (2000) Dukeite, Bi3+24Cr6+8O57(OH)6(H2O)3, a new mineral from Brejaúba, Minas Gerais, Brazil: Description and crystal structure. American Mineralogist, 85 (11) 1822-1827 doi:10.2138/am-2000-11-1227 DOI: 10.2138/am-2000-11-1227
  2. 2001Mandarino, Joseph A. (2001) New minerals. The Canadian Mineralogist, 39 (5) 1473-1502 doi:10.2113/gscanmin.39.5.1473 DOI: 10.2113/gscanmin.39.5.1473
  3. 2021(2021) Dukeite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Dukeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/dukeite-7089},
  note      = {Accessed 2026-05-11}
}