Ecdemite

Pb6As2O7Cl4
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ecd
Discovered
1877
Also known as
  • Ecdemiet
  • Ecdemit
  • Ekdemita
  • +2 more

Where it forms, where it's found

Geological setting

Metamorphosed Fe-Mn ore body.

Type locality
Långban Mine
  1. Långban Ore District
  2. Filipstad
  3. Värmland County
  4. Sweden

59.8554°, 14.2648°

17recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Translucent
Colour
Greenish-yellow · yellow
Streak
Light yellow
Cleavage
Distinct/Good

On (001), distinct.

Density
7.14 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
2.25 – 2.32
Surface relief
Very high
Principal indices
nω 2.32 · nε 2.25
Michel-Lévy diagramhighlighted lineδ = 0.0700
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]700 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation700 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21
Cell parameters
a = 10.82(4) Å · b = 10.826(2) Å · c = 6.97(1) Å
Cell angles
β = 113.26(2) °
Ratio a:b:c
1 : 1.001 : 0.644
Morphology

Crystals small tabular and in foliated masses.

Comment

from structure refinement by Perchiazzi et al. (2019), Harstigen material; previously thought to be tetragonal.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead6207.2001243.200
75.49%
33AsArsenicArsenic274.922149.844
9.10%
17ClChlorineChlorine435.450141.800
8.61%
8OOxygenOxygen715.999111.993
6.80%
Total1646.837100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ecdemiet
  • Ecdemit
  • Ekdemita
  • Ekdemite
  • Heliophyllite

In other languages

French
ecdémite
German
Ekdemit
Spanish
Ecdemita
Italian
Ecdemite

Classification

Strunz
10th ed.

3.DC.65

  • 3HalidesClass
  • 3.DOxyhalides, hydroxyhalides and related double halidesDivision
  • 3.DCWith Pb (As,Sb,Bi), without CuGroup
  • 3.DC.65EcdemiteSpecies
Dana
8th ed.

46.02.01.01

  • 46Antimonites and Arsenites Containing Hydroxyl or HalogenClass
  • 46.02MiscellaneousType
  • 46.02.01— unnamed intermediate level —Group
  • 46.02.01.01EcdemiteSpecies
CIM

23.7

  • 23ArsenitesClass
  • 23.7— unnamed intermediate level —Group
  • 23.7EcdemiteSpecies

Literature, links & citation

Citations
  1. 1889Hamberg (1889) Geologiska Föeningens I Stockholm. Förhandlinger, Stockholm: 11: 229.
  2. 1892Dana, Edward Salisbury; Dana, James Dwight (1892) A System of Mineralogy (6th ed.). John Wiley & Sons, Inc.
  3. 1921Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 DOI: 10.3133/b679
  4. 1941Sillén, Lars Gunnar, Melander, Lars (1941) X-Ray Studies on the Oxyhalide Minerals Nadorite (Ochrolite) PbSbO2Cl and Ekdemite. Zeitschrift für Kristallographie, 103 (1) 420 doi:10.1524/zkri.1941.103.1.420 DOI: 10.1524/zkri.1941.103.1.420
  5. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ecdemite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ecdemite-1363},
  note      = {Accessed 2026-05-11}
}