Edtollite

K2NaCu5Fe3+O2(AsO4)4
IMA status
  • Approved
IMA symbol
Edt
IMA approved
2016
Also known as
  • Edtolliet
  • IMA2016-010

Where it forms, where it's found

Geological setting

Fumarole.

Type locality
Arsenatnaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.6833°, 160.2333°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Colour
Brown–black to black
Density
4.26 g/cm³

Optical

Pleochroism
Not Visible
Optical colour
Grey
Anisotropism
Distinct
Bireflectance
Very weak
Internal reflections
Weak, brown
Tropism
Anisotropic
Reflectance R%
(7.0,6.8) 400, (7.1,7.2) 420, (7.8,7.8) 440, (8.1,8.2) 460, (8.3,8.2) 470, (8.4,8.2) 480, (8.2,7.9) 500, (8.0,7.7) 520, (7.8,7.5) 540, (7.7,7.4) 546, (7.6,7.3) 560, (7.2,7.0) 580, (7.1,6.9) 589, (6.9,6.8) 600, (6.6,6.5) 620, (6.4,6.3) 640, (6.3,6.3) 650, (6.3,6.2) 660, (6.2,6.2) 680, (6.3,6.4) 700
Reflected-light panel
7.3 %anisotropic · dual curve
Specimen sRGB 99, 73, 38
White reference100 % reflector under same lamp
R₁ R₂
Mode
Bireflectance
Very weak
Anisotropism
Distinct
Reflected colour
Grey
Internal reflections
Weak, brown

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 5.1168(6) Å · b = 9.124(1) Å · c = 9.698(1) Å
Cell angles
α = 110.12(1) ° · β = 102.45(1) ° · γ = 92.85(1) °
Ratio a:b:c
1 : 1.783 : 1.895
Unit cell volume
411.32 ų
Z
1
Type-locality form

Prismatic crystals up to 0.02 mm × 0.1 mm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper563.546317.730
29.90%
33AsArsenicArsenic474.922299.688
28.21%
8OOxygenOxygen1815.999287.982
27.11%
19KPotassiumPotassium239.09878.196
7.36%
26FeIronIron155.84555.845
5.26%
11NaSodiumSodium122.99022.990
2.16%
Total1062.431100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Edtolliet
  • IMA2016-010

In other languages

German
Edtollit · IMA 2016-010

Classification

Strunz
10th ed.

8.AC

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ACWith medium-sized and large cationsGroup
  • 8.ACEdtolliteSpecies

Literature, links & citation

Citations
  1. 2016Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2016) New minerals and nomenclature modifications approved in 2016, CNMNC Newsletter no 31. Mineralogical Magazine, 80 (4) 691-697 doi:10.1180/minmag.2016.080.083DOI: 10.1180/minmag.2016.080.083
  2. 2019Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Ksenofontov, Dmitry A., Pautov, Leonid A., Sidorov, Evgeny G., Britvin, Sergey N., Vigasina, Marina F., Pushcharovsky, Dmitry Y. (2019) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. X. Edtollite, K2NaCu5Fe3+O2(AsO4)4, and alumoedtollite, K2NaCu5AlO2(AsO4)4. Mineralogical Magazine, 83 (4) 485-495 doi:10.1180/mgm.2018.155 DOI: 10.1180/mgm.2018.155
  3. 2022(2022) Edtollite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Edtollite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/edtollite-47796},
  note      = {Accessed 2026-05-11}
}