Ercitite

NaMn3+(PO4)(OH) · 2H2O
IMA status
  • Approved
IMA symbol
Erc
Also known as
  • Ercitiet
  • IMA1999-036

Where it forms, where it's found

Type locality
Tanco Mine
  1. Bernic Lake
  2. Lac-du-Bonnet area
  3. Manitoba
  4. Canada

50.4300°, -95.4464°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Translucent
Colour
Pale brown · dark brown to black in aggregates
Streak
Beige
Tenacity
brittle
Cleavage
Very Good

parallel (100) and (001)

Fracture
Irregular/Uneven
Density
2.77 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 86° · 2V calc = 82°
Refractive index
1.699 – 1.737
Surface relief
High
Principal indices
nα 1.699 · nβ 1.715 · nγ 1.737
Pleochroism
Strong

X = yellowish green, Y = yellowish brown, Z = dark brown.

Dispersion
relatively strong
Michel-Lévy diagramhighlighted lineδ = 0.0380
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]380 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation380 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Cmca
Cell parameters
a = 6.2499(6) Å · b = 8.7479(9) Å · c = 19.9554(17) Å
Ratio a:b:c
1 : 1.400 : 3.193
Z
4
Type-locality form

lath-like crystals

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen715.999111.993
49.57%
25MnManganeseManganese154.93854.938
24.32%
15PPhosphorusPhosphorus130.97430.974
13.71%
11NaSodiumSodium122.99022.990
10.17%
1HHydrogenHydrogen51.0085.040
2.23%
Total225.935100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ercitiet
  • IMA1999-036

In other languages

German
Ercitit · IMA 1999-036
Italian
Ercitite
Chinese
水羟磷钠锰石

Classification

Strunz
10th ed.

8.DJ.35

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DJWith large and medium-sized cations, (OH, etc.):RO4 = 1:1Group
  • 8.DJ.35ErcititeSpecies

Literature, links & citation

Citations
  1. 2000Fransolet, Andre-Mathieu, Cooper, Mark A., Černý, Petr, Hawthorne, Frank C., Chapman, Ron, Grice, Joel D. (2000) The Tanco Pegmatite at Bernic Lake, southeastern Manitoba. XV. Ercitite, NaMn3+PO4(OH)(H2O)2, a new phosphate species. The Canadian Mineralogist, 38 (4) 893-898 doi:10.2113/gscanmin.38.4.893 DOI: 10.2113/gscanmin.38.4.893
  2. 2009Cooper, M. A., Hawthorne, F. C., Cerny, P. (2009) The crystal structure of ercitite, Na2(H2O)4[Mn3+2(OH)2(PO4)2], and its relation to bermanite, Mn2+(H2O)4[Mn3+2(OH)2(PO4)2]. The Canadian Mineralogist, 47 (1) 173-180 doi:10.3749/canmin.47.1.173 DOI: 10.3749/canmin.47.1.173
  3. 2020(2020) Ercitite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ercitite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ercitite-7101},
  note      = {Accessed 2026-05-11}
}