Eriochalcite

CuCl2 · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ech
Discovered
1870
Also known as
  • Antofagasit
  • Antofagasita
  • Antofagasite
  • +5 more

Where it forms, where it's found

Geological setting

Active volcanic fumaroles.

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
17recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Bluish green · greenish blue · yellowish tint at times.
Cleavage
Perfect

On (110) perfect; on (001) good.

Fracture
Conchoidal
Density
2.47 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 75° · 2V calc = 82°
Refractive index
1.646 – 1.745
Surface relief
High
Principal indices
nα 1.646 · nβ 1.685 · nγ 1.745
Dispersion
weak
Michel-Lévy diagramhighlighted lineδ = 0.0990
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]990 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation990 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Pmna
Cell parameters
a = 8.047 Å · b = 3.725 Å · c = 7.376 Å
Ratio a:b:c
1 : 0.463 : 0.917
Z
2
Morphology

Lichen-like aggregates of crystals elongated [01]. The center of these aggregates is occupied by small, deeply grooved spire-like cvrystals, often bent or entirely recurved as with gypsum "flowers"; wool-like aggregates.

Twinning

On (021), as nearly rectangular penetration twins.

Comment

Also given as (Pbmn setting): a = 7.38, b = 8.04, c = 3.72 A.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
17ClChlorineChlorine235.45070.900
41.59%
29CuCopperCopper163.54663.546
37.28%
8OOxygenOxygen215.99931.998
18.77%
1HHydrogenHydrogen41.0084.032
2.36%
Total170.476100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Antofagasit
  • Antofagasita
  • Antofagasite
  • Antofagastite
  • Eriocalco
  • Eriochalciet
  • Erythrocalcite
  • Erythrochalcit

In other languages

German
Eriochalcit
Italian
Eriocalcite

Classification

Strunz
10th ed.

3.BB.05

  • 3HalidesClass
  • 3.BSimple halides, with H2ODivision
  • 3.BBM:X = 1:2Group
  • 3.BB.05EriochalciteSpecies
Dana
8th ed.

09.02.08.01

  • 09Normal HalidesClass
  • 09.02AX2Type
  • 09.02.08— unnamed intermediate level —Group
  • 09.02.08.01EriochalciteSpecies
CIM

8.2.3

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.2Halides of CuGroup
  • 8.2.3EriochalciteSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. 1870Scacchi, A. (1870) Dell'eriocalco e del melanotallo, nuove specie di minerali. Rendiconto dell'Accademia delle Scienze Fisiche e Matematiche (sezione della Societa reale di Napoli): 9: 86-89.
  2. 1884Scacchi (1884) Reale accademia delle scienze fisische e matematiche, Naples: 23: 158. (as eriocalco)
  3. 1892Dana, Edward Salisbury; Dana, James Dwight (1892) A System of Mineralogy (6th ed.). John Wiley & Sons, Inc.
  4. 1898Groth, F. (1898) Tabellarische Übersicht der Einfachen Mineralien (4th ed.). Friedrich Vieweg und Sohn.
  5. 1936MacGillavry, C.H., Bijvoet, J.M. (1936) Die kristallstruktur der cadmium-und quecksilber-diammin-dihalogenide. Zeitschrift für Kristallographie: 94: 231-245.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Eriochalcite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/eriochalcite-1398},
  note      = {Accessed 2026-05-11}
}