Esperanzaite

NaCa2Al2(AsO4)2F4(OH) · 2H2O
IMA status
  • Approved
IMA symbol
Epz
Discovered
1998
IMA approved
1998
Also known as
  • Esperanzaiet
  • IMA1998-025

Where it forms, where it's found

Geological setting

Found on an altered rhyolite.

Type locality
La Esperanza Mine
  1. Francisco I. Madero
  2. Pánuco de Coronado Municipality
  3. Durango
  4. Mexico

24.3792°, -104.2917°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Pale blue-green
Streak
White
Tenacity
brittle
Cleavage
Perfect

Parallel to c.

Fracture
None observed
Density
3.24 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 74° · 2V calc = 76°
Refractive index
1.58 – 1.593
Surface relief
Moderate
Principal indices
nα 1.580 · nβ 1.588 · nγ 1.593
Pleochroism
Non-pleochroic
Dispersion
r < v moderate
Extinction
Y = b; X ∧ c = 35°; Z ∧ a = 50.5°.
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0130
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]130 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation130 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/m
Cell parameters
a = 9.687(5) Å · b = 10.7379(6) Å · c = 5.5523(7) Å
Cell angles
β = 105.32 °
Ratio a:b:c
1 : 1.108 : 0.573
Z
2
Morphology

Botryoidal patches and radiating crystals in spheres.

Type-locality form

Botryoidal pale blue-green (seafoam green) patches up to 8 mm across and separated spheres up to 1.5 mm in diameter of radiating crystals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1115.999175.989
31.21%
33AsArsenicArsenic274.922149.844
26.57%
20CaCalciumCalcium240.07880.156
14.21%
9FFluorineFluorine418.99875.992
13.47%
13AlAluminiumAluminium226.98253.964
9.57%
11NaSodiumSodium122.99022.990
4.08%
1HHydrogenHydrogen51.0085.040
0.89%
Total563.975100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Esperanzaiet
  • IMA1998-025

In other languages

German
Esperanzait · IMA 1998-025
Italian
Esperanzaite

Classification

Strunz
10th ed.

8.DM.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DMWith large and medium-sized cations, (OH, etc.):RO4 > 2:1Group
  • 8.DM.05EsperanzaiteSpecies

Literature, links & citation

Citations
  1. 1999Foord, E.E., Hughes, J.M., Cureton, F.F. II, Maxwell, C.H., Falster, A.U., Sommer, A.J., Hlava, P.F. (1999): Esperanzaite, NaCa2Al2(As5+O4)2F4(OH)•2H2O, a new mineral species from the La Esperanza mine, Mexico: descriptive mineralogy and atomic arrangement. Canadian Mineralogist 37, 67-72
  2. 2005(2005) Esperanzaite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Esperanzaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/esperanzaite-6919},
  note      = {Accessed 2026-05-11}
}