Ferraioloite

MgMn2+4(Fe2+0.5Al0.5)4Zn4(PO4)8(OH)4(H2O)20
IMA status
  • Approved
IMA symbol
Frl
IMA approved
2015
Also known as
  • Ferraioloiet
  • IMA2015-066

Where it forms, where it's found

Geological setting

vugs in a thin sugary fine-grained pegmatite seam

Type locality
Foote Lithium Co. Mine
  1. Kings Mountain
  2. Cleveland County
  3. North Carolina
  4. USA

35.2111°, -81.3556°

2recorded occurrences
Source · OpenStreetMap

Optical

Optical type
Biaxial (-) · 2V measured = 40° · 2V calc = 40°
Refractive index
1.575 – 1.5835
Surface relief
Moderate
Principal indices
nα 1.575 · nβ 1.5825 · nγ 1.5835
Pleochroism

colourless (X, Z), blue grey (Y)

Dispersion
weak (r>v)
Michel-Lévy diagramhighlighted lineδ = 0.0085
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]85 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation85 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 25.333(3) Å · b = 6.299(1) Å · c = 15.161(3) Å
Cell angles
β = 90.93(3) °
Ratio a:b:c
1 : 0.249 : 0.598
Unit cell volume
2419 ų
Morphology

platelets, blades

Type-locality form

platelets and blades up to ca. 0.2 mm long and a few μm thick

Comment

I2/m

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen5615.999895.944
48.19%
30ZnZincZinc465.380261.520
14.06%
15PPhosphorusPhosphorus830.974247.792
13.33%
25MnManganeseManganese454.938219.752
11.82%
26FeIronIron255.845111.690
6.01%
13AlAluminiumAluminium226.98253.964
2.90%
1HHydrogenHydrogen441.00844.352
2.38%
12MgMagnesiumMagnesium124.30524.305
1.31%
Total1859.319100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ca

Synonyms

  • Ferraioloiet
  • IMA2015-066

In other languages

German
Ferraioloit · IMA 2015-066
Arabic
فيرايولويت

Classification

Strunz
10th ed.

8.CF

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CFWith large and medium-sized cations, RO4:H2O > 1:1Group
  • 8.CFFerraioloiteSpecies

Literature, links & citation

Citations
  1. 2015Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2015) New minerals and nomenclature modifications approved in 2015, CNMNC Newsletter no 28. Mineralogical Magazine, 79 (7) 1859-1864 doi:10.1180/minmag.2015.079.7.18DOI: 10.1180/minmag.2015.079.7.18
  2. 2016Mills, Stuart J., Grey, Ian E., Kampf, Anthony R., MaCrae, Colin M., Smith, Jason B., Davidson, Cameron J., Glenn, A. Matt (2016) Ferraioloite, MgMn2+4(Fe2+0.5Al3+0.5)4Zn4(PO4)8(OH)4(H2O)20, a new secondary phosphate mineral from the Foote mine, USA. European Journal of Mineralogy, 28 (3) 655-661 doi:10.1127/ejm/2016/0028-2525 DOI: 10.1127/ejm/2016/0028-2525
  3. 2022(2022) Ferraioloite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ferraioloite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ferraioloite-46878},
  note      = {Accessed 2026-05-11}
}