Ferrarisite

Ca5(AsO3OH)2(AsO4)2 · 9H2O
IMA status
  • Approved
IMA symbol
Fer
Discovered
1980
Also known as
  • Ferrarisiet
  • IMA1979-020
  • Unnamed (Ca Arsenate Hydrate III)

Where it forms, where it's found

Geological setting

Oxidized vein assemblages in arsenic-rich mines

Type locality
Gabe Gottes Mine
  1. Sankt Jakob vein
  2. Neuenberg
  3. Sainte-Marie-aux-Mines
  4. Colmar-Ribeauvillé
  5. Haut-Rhin
  6. Grand Est
  7. France

48.2136°, 7.1589°

15recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Transparent · Translucent
Colour
Colorless to white

White mineral may be dehydrated to unspecified minerals

Streak
White
Tenacity
brittle
Cleavage
Perfect

(001) perfect

Density
2.63 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 83° · 2V calc = 84°
Refractive index
1.562 – 1.585
Surface relief
Moderate
Principal indices
nα 1.562 · nβ 1.572 · nγ 1.585
Birefringence
0.023
Pleochroism
Non-pleochroic
Dispersion
strong
Extinction
X ^ c = 8°-17°; Z perpendicular to {110}
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0230
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]230 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation230 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
P-1
Cell parameters
a = 8.294 Å · b = 6.722 Å · c = 11.198 Å
Cell angles
α = 106.16 ° · β = 92.94 ° · γ = 99.20 °
Ratio a:b:c
1 : 0.810 : 1.350
Z
1
Type-locality form

White radiating very elongated crystals.

Comment

Bull Min. (1980): 103:541 structure

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2515.999399.975
43.46%
33AsArsenicArsenic474.922299.688
32.57%
20CaCalciumCalcium540.078200.390
21.78%
1HHydrogenHydrogen201.00820.160
2.19%
Total920.213100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ferrarisiet
  • IMA1979-020
  • Unnamed (Ca Arsenate Hydrate III)

In other languages

French
Ferrarisite
German
Ferrarisit · IMA 1979-020
Italian
Ferrarisite

Classification

Strunz
10th ed.

8.CJ.30

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CJWith only large cationsGroup
  • 8.CJ.30FerrarisiteSpecies
Dana
8th ed.

39.02.03.01

  • 39Hydrated Acid Phosphates, Arsenates and VanadatesClass
  • 39.02(AB)5[HXO4]2[XO4]2.xH2OType
  • 39.02.03— unnamed intermediate level —Group
  • 39.02.03.01FerrarisiteSpecies
CIM

20.2.12

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.2Arsenates of Be, Mg, Ca or BaGroup
  • 20.2.12FerrarisiteSpecies

Literature, links & citation

Citations
  1. 1980Bulletin de Mineralogie (1980): 103: 533-540.
  2. 1980Bulletin de Mineralogie (1980): 103: 541-546, structure.
  3. 1981Fleischer, Michael, Cabri, Louis J. (1981) New Mineral Names. American Mineralogist, 66 (5-6) 637-639
  4. 1981Catti, M. & Ivaldi, G. (1981) Mechanism of the reaction Ca5H2(AsO4)4•9H2O (ferrarisite) -> Ca5H2(AsO4)4•5H2O (dimorph of vladimirite) and structure of the latter phase. Z. Kristallogr., 157, 119-130.
  5. 2005(2005) Ferrarisite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ferrarisite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ferrarisite-1485},
  note      = {Accessed 2026-05-11}
}