Ferriphoxite

[(NH4)2K(H2O)][Fe3+(HPO4)2(C2O4)]
IMA status
  • Approved
IMA symbol
Fphx
IMA approved
2024
Also known as
  • Ferriphoxiet

Where it forms, where it's found

Geological setting

bat-guano-related, post-mining assemblage.

Type locality
125 foot level
  1. Rowley Mine
  2. Theba
  3. Painted Rock Mining District
  4. Painted Rock Mountains
  5. Maricopa County
  6. Arizona
  7. USA

33.0492°, -113.0330°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
colorless
Streak
white
Tenacity
brittle
Cleavage
Distinct/Good

three good cleavages ((100), (010) and (001))

Fracture
Splintery
Density
2.14 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 83.9°
Refractive index
1.524 – 1.608
Surface relief
Moderate
Principal indices
nα 1.524 · nβ 1.560 · nγ 1.608
Pleochroism
Non-pleochroic
Dispersion
distinct r < v dispersion
UV response
The mineral does not fluoresce in either long- or shortwave ultraviolet illumination
Notes

good way to distinguish carboferriphoxite from ferriphoxite is by its distinctly higher birefringence, evidenced by higher order interference colours under crossed polars.

Michel-Lévy diagramhighlighted lineδ = 0.0840
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]840 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation840 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 11.389(5) Å · b = 6.352(3) Å · c = 18.716(9) Å
Cell angles
β = 102.887(9) °
Ratio a:b:c
1 : 0.558 : 1.643
Z
4
Twinning

No twinning was observed.

Type-locality form

rectangular blades, up to about 0.1 mm in length, typically forming sprays

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1315.999207.987
48.48%
15PPhosphorusPhosphorus230.97461.948
14.44%
26FeIronIron155.84555.845
13.02%
19KPotassiumPotassium139.09839.098
9.11%
7NNitrogenNitrogen214.00728.014
6.53%
6CCarbonCarbon212.01124.022
5.60%
1HHydrogenHydrogen121.00812.096
2.82%
Total429.010100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From Mindat formula

Synonyms

  • Ferriphoxiet

In other languages

German
Ferriphoxit

Classification

Strunz
10th ed.

10.AB.60

  • 10Organic CompoundsClass
  • 10.ASalts of organic acidsDivision
  • 10.ABOxalatesGroup
  • 10.AB.60FerriphoxiteSpecies

Literature, links & citation

Citations
  1. 2024Bosi, Ferdinando, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2024) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 77. European Journal of Mineralogy, 36 (1). 165-172 doi:10.5194/ejm-36-165-2024DOI: 10.5194/ejm-36-165-2024
  2. 2025Kampf, Anthony R.; Ma, Chi; Hawthorne, Frank C.; Marty, Joe (2025) Ferriphoxite and carboferriphoxite: two new oxalato-phosphate minerals from the Rowley mine, Arizona, USA. Mineralogical Magazine, 89 (1). 148-154 doi:10.1180/mgm.2024.56DOI: 10.1180/mgm.2024.56
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ferriphoxite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ferriphoxite-470990},
  note      = {Accessed 2026-05-11}
}