Fillowite

Na3CaMn2+11(PO4)9
IMA status
  • Approved
  • Grandfathered
IMA symbol
Fil
Discovered
1879
Also known as
  • Fillowiet

Where it forms, where it's found

Geological setting

Granite pegmatite containing lithiophilite.

Type locality
Fillow Quarry
  1. Branchville
  2. Redding
  3. Fairfield County
  4. Connecticut
  5. USA

41.2678°, -73.4392°

10recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Greenish yellow to yellow green · yellowish brown · reddish brown · colourless · colourless to yellow in transmitted light.
Streak
White
Tenacity
brittle
Cleavage
Perfect

On (001), nearly perfect.

Fracture
Irregular/Uneven
Density
3.43 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.671 – 1.676
Surface relief
High
Principal indices
nω 1.671 – 1.672 · nε 1.676
Birefringence
0.005
Dispersion
r < v strong
UV response
Not fluorescent.
Notes

May be anomalously biaxial (+). 1.672, 1.672, 1.676. 2V = 30°

Michel-Lévy diagramhighlighted lineδ = 0.0050
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]50 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation50 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
R-3
Cell parameters
a = 15.25 Å · c = 43.32 Å
Z
18
Morphology

Granular crystalline masses, rarely as tiny <<1 mm pseudo-cubic rhombohedra in intergrown columns (<< 1 mm).

Comment

ICDD 18-516; Am Min 74:918 structure

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese1154.938604.318
38.54%
8OOxygenOxygen3615.999575.964
36.73%
15PPhosphorusPhosphorus930.974278.766
17.78%
11NaSodiumSodium322.99068.970
4.40%
20CaCalciumCalcium140.07840.078
2.55%
Total1568.096100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Fillowiet

In other languages

German
Fillowit
Italian
fillowite

Classification

Strunz
10th ed.

8.AC.50

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ACWith medium-sized and large cationsGroup
  • 8.AC.50FillowiteSpecies
Dana
8th ed.

38.02.05.01

  • 38Anhydrous Normal Phosphates, Arsenates, and VanadatesClass
  • 38.02(AB)5(XO4)3Type
  • 38.02.05Fillowite GroupGroup
  • 38.02.05.01FillowiteSpecies
CIM

19.12.30

  • 19PhosphatesClass
  • 19.12Phosphates of MnGroup
  • 19.12.30FillowiteSpecies

Group, growth & confusion

In the same group
3 members

Literature, links & citation

Citations
  1. 1879Brush, G.J., Dana, E.S. (1879) On the mineral locality in Fairfield County, Connecticut, with the description of two additional new species. Second Paper. American Journal of Science and Arts, 17, 359-368 (363).
  2. 1879Brush and Dana (1879) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 3: 578.
  3. 1890Brush, G.J., Dana, E.S., Wells, H.L. (1890) On the mineral locality at Branchville, Connecticut: Fifth paper. American Journal of Science, 39, 201-216 (215, Wells' analysis).
  4. 1921Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 DOI: 10.3133/b679
  5. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Fillowite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/fillowite-1549},
  note      = {Accessed 2026-05-11}
}