Flinkite

Mn2+2Mn3+(AsO4)(OH)4
IMA status
  • Approved
  • Grandfathered
IMA symbol
Fln
Discovered
1889
Also known as
  • Flinkiet

Where it forms, where it's found

Geological setting

Metamorphosed Mn-Fe ore body of the Långban type.

Type locality
Harstigen Mine
  1. Pajsberg
  2. Persberg ore district
  3. Filipstad
  4. Värmland County
  5. Sweden

59.7853°, 14.3139°

8recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Green-brown · dark green · brownish yellow-green in transmitted light.
Tenacity
brittle
Density
3.87 g/cm³

Optical

Optical type
Biaxial (+)
Refractive index
1.783 – 1.834
Surface relief
Very high
Principal indices
nα 1.783 · nβ 1.801 · nγ 1.834
Pleochroism
Visible

X = b = Pale brownish green Y = c = Yellow-green Z = a = Orange-brown

Dispersion
extreme
Notes

2V large.

Michel-Lévy diagramhighlighted lineδ = 0.0510
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]510 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation510 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#71
Cell parameters
a = 9.483(2) Å · b = 13.030(3) Å · c = 5.339(1) Å
Ratio a:b:c
1 : 1.374 : 0.563
Z
4
Morphology

Crystals thin tabular (001) with minor elongation [010]. The crystals are frequently rounded in the zone [100], and (001) is striated [100]. Individuals rare, commonly as feather-like aggregates.

Type-locality form

Veinlets in magnetite ore.

Comment

Data from Kolitsch (2001) (sample from type locality; from collection of Natural History Museum Vienna, cat. no. F9361).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese354.938164.814
44.33%
8OOxygenOxygen815.999127.992
34.43%
33AsArsenicArsenic174.92274.922
20.15%
1HHydrogenHydrogen41.0084.032
1.09%
Total371.760100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Flinkiet

In other languages

German
Flinkit
Italian
Flinkite
Chinese
褐砷锰石

Classification

Strunz
10th ed.

8.BE.30

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BEWith only medium-sized cations, (OH, etc.):RO4 > 2:1Group
  • 8.BE.30FlinkiteSpecies
Dana
8th ed.

41.03.03.01

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.03(AB)3(XO4)ZqType
  • 41.03.03— unnamed intermediate level —Group
  • 41.03.03.01FlinkiteSpecies
CIM

20.8.4

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.8Arsenates of MnGroup
  • 20.8.4FlinkiteSpecies

Literature, links & citation

Citations
  1. 1889Hamberg, Axel (1889) Mineralogische Studien. 6 Optische Anomalien des Ekdemit (Heliophyllit) von Harstigen. Geologiska Föreningen i Stockholm Förhandlingar, 11 (4) 229-237 doi:10.1080/11035898909444257DOI: 10.1080/11035898909444257
  2. 1921Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 DOI: 10.3133/b679
  3. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  4. 1967Moore, Paul B. (1967) Crystal chemistry of the basic manganese arsenate minerals: I. The crystal structures of flinkite, Mn2+2Mn3+(OH)4(AsO4) and retzian, Mn2+2Y3+(OH)4(AsO4) American Mineralogist, 52 (11-12) 1603-1613
  5. 1969Welin, E. (1969) Notes on the mineralogy of Sweden 6. X-ray powder data for minerals from Långban and the related mineral deposits of Central Sweden. Arkiv för Mineralogi och Geologi, 4 (6, nr 30). 499-541
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Flinkite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/flinkite-1558},
  note      = {Accessed 2026-05-11}
}