Fresnoite

Ba2TiO(Si2O7)
IMA status
  • Approved
IMA symbol
Fno
Discovered
1960
Also known as
  • Fresnoiet
  • IMA1964-012

Where it forms, where it's found

Geological setting

Gneissic metamorphic rocks composed mainly of sanbornite and quartz.

Type locality
Esquire No. 7 claim
  1. Big Creek
  2. Big Creek-Rush Creek Mining District
  3. Fresno County
  4. California
  5. USA

36.9167°, -119.2450°

26recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Lemon to canary yellow
Streak
White
Cleavage
Imperfect/Fair

(001)

Density
4.43 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.765 – 1.775
Surface relief
High
Principal indices
nω 1.775 · nε 1.765
Pleochroism
Visible

In transmitted polarized light, from yellow to colorless. The mineral characteristically shows anomalous blueinterference colors.

UV response
Pale yellow under SW UV @ 265.2 nm. No fluorescence under LW UV @ 365.0 nm.
Michel-Lévy diagramhighlighted lineδ = 0.0100
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]100 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation100 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
#161
Cell parameters
a = 8.52 Å · c = 5.21 Å
Z
2
Type-locality form

Sparse grains, generally less than 1 mm long.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
56BaBariumBarium2137.327274.654
54.21%
8OOxygenOxygen815.999127.992
25.26%
14SiSiliconSilicon228.08556.170
11.08%
22TiTitaniumTitanium147.86747.867
9.45%
Total506.683100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Al
  • Fe
  • Mn
  • Mg
  • Ca
  • Sr
  • K

Synonyms

  • Fresnoiet
  • IMA1964-012

In other languages

German
Fresnoit · IMA 1964-012
Italian
Fresnoite

Classification

Strunz
10th ed.

9.BE.15

  • 9SilicatesClass
  • 9.BSorosilicatesDivision
  • 9.BESi2O7 groups, with additional anions; cations in octahedral [6] and greater coordinationGroup
  • 9.BE.15FresnoiteSpecies
Dana
8th ed.

55.04.02.01

  • 55Sorosilicates Si2o7 Groups, Generally with No Additional AnionsClass
  • 55.04Si2O7 Groups, Generally with No Additional Anions with cations in [8] and lower coordinationType
  • 55.04.02Fresnoite groupGroup
  • 55.04.02.01FresnoiteSpecies
CIM

14.9.11

  • 14Silicates not Containing AluminumClass
  • 14.9Silicates of TiGroup
  • 14.9.11FresnoiteSpecies

Group, growth & confusion

Often grow together
2 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. Halliyal, A.; Bhalla, A. S.; Markgraf, S. A.; Cross, L. E.; Newnham, R. E. (1985): Unusual pyroelectric and piezoelectric properties of fresnoite (Ba2TiSi2O8) single crystal and polar glass-ceramics. Ferroelectrics 62(1-2), 27-38.
  2. Markgraf, S. A.; Sharm, S. K.; Bhalla, A. S. (1993): Raman study of fresnoite-type materials: polarized single crystal, crystalline powders, and glasses. Journal of Materials Research 8(3), 635-648.
  3. Markgraf, S. A.; Halliyal, A.; Bhalla, A. S.; Newnham, R. E.; Prewitt, C. T. (1985): X-ray structure refinement and pyroelectric investigation of fresnoite, Ba2TiSi2O8. Ferroelectrics 62(1-2), 17-26.
  4. Völtzke, Dieter; Müller, Thomas; Abicht, Hans Peter; Freude, Dieter (1991): Zur Synthese von reinem Fresnoit [On the synthesis of pure fresnoite]. Silikattechnik 42(9), 313-318. (In German.)
  5. 1965Alfors, John T., Stinson, Melvin C., Matthews, Robert A., Pabst, Adolf (1965) Seven new barium minerals from eastern Fresno County, California. American Mineralogist, 50 (3-4) 314-340
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Fresnoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/fresnoite-1607},
  note      = {Accessed 2026-05-11}
}