Freudenbergite

Na(Ti4+3Fe3+)O8
IMA status
  • Approved
IMA symbol
Fdb
Discovered
1961
Also known as
  • Freudenbergiet

Where it forms, where it's found

Geological setting

Apatite-rich alkali syenite. Of late magmatic origin.

Type locality
Michelsberg Quarry
  1. Katzenbuckel
  2. Waldkatzenbach
  3. Waldbrunn
  4. Neckar-Odenwald-Kreis
  5. Karlsruhe Region
  6. Baden-Württemberg
  7. Germany

49.4694°, 9.0447°

9recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Black · deep brown to light yellowish brown in transmitted light
Streak
Pale yellow-brown
Cleavage
Distinct/Good

(001), and another prismatic, good.

Density
3.956 g/cm³

Optical

Optical type
Biaxial (+)
Refractive index
2.37 – 2.42
Surface relief
Very high
Principal indices
nβ 2.37 – 2.42
Pleochroism
Visible

Deep brown to pale yellow-brown.

Dispersion
r < v
Internal reflections
yellow-brown
Notes

n = ∼2.37–2.42

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 12.3 Å · b = 3.82 Å · c = 6.5 Å
Cell angles
β = 107.3 °
Ratio a:b:c
1 : 0.311 : 0.528
Z
4
Type-locality form

Irregularly shaped grains, to 0.15 mm.

Comment

Point Group: 2/m, m,or 2. Space Group: C2/m, Cm,or C2.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
22TiTitaniumTitanium347.867143.601
40.98%
8OOxygenOxygen815.999127.992
36.52%
26FeIronIron155.84555.845
15.94%
11NaSodiumSodium122.99022.990
6.56%
Total350.428100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Freudenbergiet

In other languages

German
Freudenbergit
Italian
Freudenbergite
Chinese
黑钛铁钠矿

Classification

Strunz
10th ed.

4.CC.10

  • 4OxidesClass
  • 4.CMetal: Oxygen = 2: 3,3: 5, and similarDivision
  • 4.CCWith large and medium-sized cationsGroup
  • 4.CC.10FreudenbergiteSpecies
Dana
8th ed.

07.09.03.01

  • 07Multiple OxidesClass
  • 07.09AB8X16Type
  • 07.09.03— unnamed intermediate level —Group
  • 07.09.03.01FreudenbergiteSpecies
CIM

7.9.19

  • 7Oxides and HydroxidesClass
  • 7.9Oxides of TiGroup
  • 7.9.19FreudenbergiteSpecies

Literature, links & citation

Citations
  1. 1961Fleischer, M. (1961) New mineral names. American Mineralogist, 46 (5-6). 765-770
  2. 1961Frenzel, G. (1961) Ein neues Mineral: Freudenbergit (Na2Fe2Ti7O18). Neues Jahrbuch für Mineralogie, Monatshefte: 1961: 12-22.
  3. 1967IMA (1967) International Mineralogical Association: Commission on New Minerals and Mineral Names. Mineralogical Magazine and Journal of the Mineralogical Society, 36 (277) 131-136 doi:10.1180/minmag.1967.036.277.20 DOI: 10.1180/minmag.1967.036.277.20
  4. 1970McKie, Duncan, Long, J. V. P. (1970) The unit-cell contents of freudenbergite. Zeitschrift für Kristallographie - Crystalline Materials, 132 (1) 157-160 doi:10.1524/zkri.1970.132.1-6.157 DOI: 10.1524/zkri.1970.132.1-6.157
  5. 1978Ishiguro, T.; Tanaka, K.; Marumo, F.; Ismail, M. G. M. U.; Hirano, S.; Sōmiya, S. (1978) Freudenbergite. Acta Crystallographica Section B, 34 (1). 255-256 doi:10.1107/s0567740878002708DOI: 10.1107/s0567740878002708
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Freudenbergite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/freudenbergite-1608},
  note      = {Accessed 2026-05-11}
}