Frolovite

Ca[B(OH)4]2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Flv
Discovered
1957
Also known as
  • Froloviet
  • Frolowit
  • Frolowita
  • +1 more

Where it forms, where it's found

Type locality
Novofrolovskoye B-Cu deposit
  1. Tur'insk
  2. Turya river
  3. Serovsky District
  4. Sverdlovsk Oblast
  5. Russia

59.7833°, 60.5000°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
White · with a grayish tint
Tenacity
brittle
Density
2.14 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 70° · 2V calc = 80°
Refractive index
1.563 – 1.586
Surface relief
Moderate
Principal indices
nα 1.563 · nβ 1.572 · nγ 1.586
Dispersion
strong
Michel-Lévy diagramhighlighted lineδ = 0.0230
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]230 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation230 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 7.774(2) Å · b = 5.680(1) Å · c = 8.136(2) Å
Cell angles
α = 113.51(1) ° · β = 101.67(2) ° · γ = 107.87(2) °
Ratio a:b:c
1 : 0.731 : 1.047
Z
2
Morphology

veinlets and dense aggregates of grains, to 0.15 mm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen815.999127.992
64.72%
20CaCalciumCalcium140.07840.078
20.27%
5BBoronBoron210.81021.620
10.93%
1HHydrogenHydrogen81.0088.064
4.08%
Total197.754100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Froloviet
  • Frolowit
  • Frolowita
  • Frolowite

In other languages

German
Frolovit
Italian
Frolovite

Classification

Strunz
10th ed.

6.AC.20

  • 6BoratesClass
  • 6.AMonoboratesDivision
  • 6.ACB(O,OH)4, without and with additional anions; 1(T), 1(T)+OH, etcGroup
  • 6.AC.20FroloviteSpecies
Dana
8th ed.

25.01.03.01

  • 25Anhydrous Borates Containing Hydroxyl or HalogenClass
  • 25.01MonoboratesType
  • 25.01.03— unnamed intermediate level —Group
  • 25.01.03.01FroloviteSpecies
CIM

9.3.7

  • 9BoratesClass
  • 9.3Borates of Ca and SrGroup
  • 9.3.7FroloviteSpecies

Literature, links & citation

Citations
  1. 1957Petrova E S (1957) A new hydrous calcium borate - frolovite. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva 86, issue 5, 622-625
  2. 1958Fleischer, M. (1958) New Mineral Names. American Mineralogist, 43 (3-4). 378-387
  3. 1972Egorov-Tismenko Y K, Gushchina A E, Shashkin D N, Simonov M A, Belov N V (1972) The crystal structure of frolovite CaB2O4(H2O)4 = Ca(B(OH)4)2. Doklady Akademii Nauk SSSR 202, 78-80
  4. 1976Казанская, Е. В., Егоров-Тисменко, Ю. К., Железин, Е. П., Белов, Н. В. (1976) Уточненная кристаллическая структура фроловита Ca[B(OH)4]2 [Refinement of the crystal structure of frolovite, Ca[B(OH)4]2]. Доклады Академии наук [Reports of the Academy of Sciences], 230 (1) 91-94
  5. 1996Grew, Edward S.; Anovitz, Lawrence M. - Eds. (1996) Boron - Mineralogy, Petrology and Geochemistry. Reviews in Mineralogy Vol. 33. Mineralogical Society of America p.862
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Frolovite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/frolovite-1613},
  note      = {Accessed 2026-05-11}
}