Galliskiite

Ca4Al2(PO4)2F8 · 5H2O
IMA status
  • Approved
IMA symbol
Glk
IMA approved
2009
Also known as
  • Galliskiiet
  • IMA2009-038

Where it forms, where it's found

Geological setting

Intragranitic pegmatites related to the Achala batholith. The parental magma was rich in fluorine.

Type locality
Gigante pegmatite
  1. Candelaria District
  2. Cruz del Eje department
  3. Córdoba Province
  4. Argentina

-31.4086°, -64.7719°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
colorless
Streak
White
Tenacity
brittle
Cleavage
Imperfect/Fair

two fair cleavages at ~90° (probably (010) and (001)).

Fracture
Irregular/Uneven · Conchoidal
Density
2.67 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 33° · 2V calc = 32°
Refractive index
1.493 – 1.52
Surface relief
Moderate
Principal indices
nα 1.493 · nβ 1.495 · nγ 1.520
Pleochroism
Non-pleochroic
Dispersion
moderate r < v
UV response
none
Michel-Lévy diagramhighlighted lineδ = 0.0270
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]270 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation270 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 6.1933(7) Å · b = 9.871(1) Å · c = 13.580(2) Å
Cell angles
α = 89.716(3) ° · β = 75.303(4) ° · γ = 88.683(4) °
Ratio a:b:c
1 : 1.594 : 2.193
Z
2
Twinning

Simple contact and polysynthetic twinning on (100) by rotation about [010] is ubiquitous.

Parting
none
Type-locality form

crystals growing on a drusy layer of morinite covering triplite. forms massive intergrown vein fillings in triplite, but always separated from it by morinite. Clearly galliskiite is a late-stage hydrothermal mineral that crystallized from fluorine-rich so

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1315.999207.987
32.18%
20CaCalciumCalcium440.078160.312
24.81%
9FFluorineFluorine818.998151.984
23.52%
15PPhosphorusPhosphorus230.97461.948
9.58%
13AlAluminiumAluminium226.98253.964
8.35%
1HHydrogenHydrogen101.00810.080
1.56%
Total646.275100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Galliskiiet
  • IMA2009-038

In other languages

German
Galliskiit · IMA 2009-038
Italian
galliskiite
Chinese
加氟磷铝钙石

Classification

Strunz
10th ed.

8.DH.65

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DHWith large and medium-sized cations, (OH, etc.):RO4 < 1:1Group
  • 8.DH.65GalliskiiteSpecies
Dana
8th ed.

42.02.02.05

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.02(AB)3(XO4)Zq·xH2OType
  • 42.02.02— unnamed intermediate level —Group
  • 42.02.02.05GalliskiiteSpecies

Literature, links & citation

Citations
  1. 2010Kampf, A. R., Colombo, F., Simmons, W. B., Falster, A. U., Nizamoff, J. W. (2010) Galliskiite, Ca4Al2(PO4)2F8 · 5H2O, a new mineral from the Gigante granitic pegmatite, Cordoba province, Argentina. American Mineralogist, 95 (2) 392-396 doi:10.2138/am.2010.3395 DOI: 10.2138/am.2010.3395
  2. 2021(2021) Galliskiite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Galliskiite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/galliskiite-39639},
  note      = {Accessed 2026-05-11}
}