Gatehouseite

Mn2+5(PO4)2(OH)4
IMA status
  • Approved
IMA symbol
Ghs
Discovered
1992
IMA approved
1992
Also known as
  • Gatehouseiet
  • Gatehousit
  • Gatehousite
  • +1 more

Where it forms, where it's found

Geological setting

A secondary mineral. The deposit is a sedimentary iron ore deposit of Precambrian age, containing pods of manganese and small amounts of zinc and phosphorous. Weathering mobilized mobilized those elements, depositing secondary minerals in fractures and cavities.

Type locality
Iron Monarch Main Pit
  1. Iron Knob
  2. Pastoral Unincorporated Area
  3. South Australia
  4. Australia

-32.7447°, 137.1395°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Adamantine
Transparency
Transparent · Translucent
Colour
Pale yellow. Occasionally light reddish orange to light reddish brown and may be confused with arsenoclasite.

Usually a shade of yellow and not red.

Streak
Pale yellow
Tenacity
brittle
Cleavage
Perfect

(010)

Fracture
Splintery
Density
3.74 g/cm³

Optical

Optical type
Biaxial (+/-)
Refractive index
1.741 – 1.761
Surface relief
High
Principal indices
nα 1.741 · nβ 1.75 · nγ 1.761
Birefringence
0.020
Pleochroism
Strong

Brown to colorless

Dispersion
r > v moderate
Extinction
Parallel, length slow
UV response
Not fluorescent in UV
Michel-Lévy diagramhighlighted lineδ = 0.0200
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]200 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation200 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
P21 21 21
Cell parameters
a = 9.097 Å · b = 5.693 Å · c = 18.002 Å
Ratio a:b:c
1 : 0.626 : 1.979
Z
4
Morphology

Isolated crystals are rare, originally less than 100 microns long. Bladed crystals show <em>c</em> (001). <em>m</em> (110), and <em>n</em> (102). Also in radiating to divergent groups.

Twinning

On (001), contact twins.

Type-locality form

Radiating to divergent groups of individual blade-like crystals up to 100 x 20 x 5 µm . Also occurs as overgrowths on arsenoclasite crystals up to 5 mm in length.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese554.938274.690
51.57%
8OOxygenOxygen1215.999191.988
36.04%
15PPhosphorusPhosphorus230.97461.948
11.63%
1HHydrogenHydrogen41.0084.032
0.76%
Total532.658100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Cu
  • Zn
  • Pb
  • Al
  • V
  • As
  • H2O

Synonyms

  • Gatehouseiet
  • Gatehousit
  • Gatehousite
  • IMA1992-016

In other languages

French
gatehouseite
German
Gatehouseit · IMA 1992-016
Spanish
gatehousita
Italian
gatehouseite
Japanese
ガテフォス石
Chinese
盖特豪斯石

Classification

Strunz
10th ed.

8.BD.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BDWith only medium-sized cations, (OH, etc.):RO4= 2:1Group
  • 8.BD.10GatehouseiteSpecies
Dana
8th ed.

41.04.01.02

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.04(AB)5(XO4)2ZqType
  • 41.04.01— unnamed intermediate level —Group
  • 41.04.01.02GatehouseiteSpecies

Literature, links & citation

Citations
  1. 1977Ruszala, F. A., Anderson, J. B., Kostiner, E. (1977) Crystal structures of two isomorphs of arsenoclasite: Co5(PO4)2(OH)4 and Mn5(PO4)2(OH)4. Inorganic Chemistry, 16 (9) 2417-2422 doi:10.1021/ic50175a051DOI: 10.1021/ic50175a051
  2. 1993Pring, A., Birch, W. D. (1993) Gatehouseite, a new manganese hydroxy phosphate from Iron Monarch, South Australia. Mineralogical Magazine, 57 (387) 309-313 doi:10.1180/minmag.1993.057.387.13 DOI: 10.1180/minmag.1993.057.387.13
  3. 1994Jambor, John L., Grew, Edward S. (1994) New Mineral Names. American Mineralogist, 79 (1-2) 185-189
  4. 1997Mandarino, Joseph A. (1997) New Minerals 1990-1994. The Mineralogical Record Inc., Tuscon, Arizona. 220pp.
  5. 2005(2005) Gatehouseite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Gatehouseite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/gatehouseite-6966},
  note      = {Accessed 2026-05-11}
}