Gengenbachite

KFe3(H2PO4)2(HPO4)4 · 6H2O
IMA status
  • Approved
IMA symbol
Gnb
IMA approved
2006
Also known as
  • Gengenbachiet
  • IMA2001-003b
  • Unnamed (K-Fe-H Phosphate)

Where it forms, where it's found

Type locality
Silberbrünnle Mine
  1. Gengenbach
  2. Gengenbach
  3. Ortenaukreis
  4. Freiburg Region
  5. Baden-Württemberg
  6. Germany

48.4375°, 8.0844°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Pale brown
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
2.4 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.592 – 1.596
Surface relief
Moderate
Principal indices
nω 1.592 · nε 1.596
Extinction
Anomalous pale brownish interference colours.
Michel-Lévy diagramhighlighted lineδ = 0.0040
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]40 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation40 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#81
Cell parameters
a = 9.12(1) Å · c = 16.84(2) Å
Z
2
Morphology

Simple hexagonal prisms.

Type-locality form

Hexagonal columnar crystals intergrown with haigerachite. The reach a maximum of about 0.06 mm in length.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3015.999479.970
53.77%
15PPhosphorusPhosphorus630.974185.844
20.82%
26FeIronIron355.845167.535
18.77%
19KPotassiumPotassium139.09839.098
4.38%
1HHydrogenHydrogen201.00820.160
2.26%
Total892.607100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Gengenbachiet
  • IMA2001-003b
  • Unnamed (K-Fe-H Phosphate)

In other languages

German
Gengenbachit · IMA 2001-003b
Italian
gengenbachite

Classification

Strunz
10th ed.

8.CA.65

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CAWith small and large/medium cationsGroup
  • 8.CA.65GengenbachiteSpecies

Literature, links & citation

Citations
  1. 1997Anisimova, N., Chudinova, N., Serafin, M. (1997) Preparation and Crystal Structure of Potassium Iron Hydrogen Phosphate, KFe3(HPO4)2(H2PO4)6 · 4 H2O. Zeitschrift für anorganische und allgemeine Chemie, 623 (11). 1708-1714 doi:10.1002/zaac.19976231106DOI: 10.1002/zaac.19976231106
  2. 1998Walenta, Kurt (1998) Neue Mineralfunde aus dem Schwarzwald. 7. Folge, 2. Teil [New mineral finds from the Black Forest. Episode 7, Part 2]. Lapis, 23 (12). 43-48
  3. 2004Walenta, K., Theye, T. (2004): KFe3+3[(H2PO4)2|(HPO4)4]•6H2O, ein zweites neues Phosphatmineral von der Grube Silberbrünnle im mittleren Schwarzwald. Der Erzgräber, 18(1), 17-23. (in German)
  4. 2005Piilonen, P. C. (2005) New mineral names. American Mineralogist, 90 (7) 1227-1232 doi:10.2138/am.2005.445DOI: 10.2138/am.2005.445
  5. 2007Walenta, K., Theye, T., Hatert, F. (2007): Gengenbachit, KFe3+3(H2PO4)2(HPO4)4•6H2O, ein zweites neues Phosphatmineral von der Grube Silberbrünnle im mittleren Schwarzwald, nunmehr eine anerkannte neue Mineralart. Aufschluss, 58, 125-128. (in German)
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Gengenbachite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/gengenbachite-29254},
  note      = {Accessed 2026-05-11}
}