Where it forms, where it's found
- Type locality
- Silberbrünnle Mine
- Gengenbach
- Gengenbach
- Ortenaukreis
- Freiburg Region
- Baden-Württemberg
- Germany
48.4375°, 8.0844°
1recorded occurrences
Physical
Optical
- Optical type
- Uniaxial (+)
- Refractive index
- 1.592 – 1.596
- Surface relief
- Moderate
- Principal indices
- nω 1.592 · nε 1.596
- Extinction
- Anomalous pale brownish interference colours.
Δ = 0Δmax
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation40 nm
Order1st order
XPL colour
Crystallography
- Space group
- #81
- Cell parameters
- a = 9.12(1) Å · c = 16.84(2) Å
- Z
- 2
- Morphology
Simple hexagonal prisms.
- Type-locality form
Hexagonal columnar crystals intergrown with haigerachite. The reach a maximum of about 0.06 mm in length.
Crystal structure
Chemical composition
Synonyms
- Gengenbachiet
- IMA2001-003b
- Unnamed (K-Fe-H Phosphate)
In other languages
- German
- Gengenbachit · IMA 2001-003b
- Italian
- gengenbachite
Classification
Strunz
10th ed.8.CA.65
- 8Phosphates, Arsenates, VanadatesClass
- 8.CPhosphates without additional anions, with H2ODivision
- 8.CAWith small and large/medium cationsGroup
- 8.CA.65GengenbachiteSpecies
Literature, links & citation
Citations
- 1997Anisimova, N., Chudinova, N., Serafin, M. (1997) Preparation and Crystal Structure of Potassium Iron Hydrogen Phosphate, KFe3(HPO4)2(H2PO4)6 · 4 H2O. Zeitschrift für anorganische und allgemeine Chemie, 623 (11). 1708-1714 doi:10.1002/zaac.19976231106DOI: 10.1002/zaac.19976231106
- 1998Walenta, Kurt (1998) Neue Mineralfunde aus dem Schwarzwald. 7. Folge, 2. Teil [New mineral finds from the Black Forest. Episode 7, Part 2]. Lapis, 23 (12). 43-48
- 2004Walenta, K., Theye, T. (2004): KFe3+3[(H2PO4)2|(HPO4)4]•6H2O, ein zweites neues Phosphatmineral von der Grube Silberbrünnle im mittleren Schwarzwald. Der Erzgräber, 18(1), 17-23. (in German)
- 2005Piilonen, P. C. (2005) New mineral names. American Mineralogist, 90 (7) 1227-1232 doi:10.2138/am.2005.445DOI: 10.2138/am.2005.445
- 2007Walenta, K., Theye, T., Hatert, F. (2007): Gengenbachit, KFe3+3(H2PO4)2(HPO4)4•6H2O, ein zweites neues Phosphatmineral von der Grube Silberbrünnle im mittleren Schwarzwald, nunmehr eine anerkannte neue Mineralart. Aufschluss, 58, 125-128. (in German)
Cite this entry
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Gengenbachite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/gengenbachite-29254},
note = {Accessed 2026-05-11}
}