Gerstleyite

Na2(Sb,As)8S13 · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Gst
Discovered
1956
Also known as
  • Gerstleyiet

Where it forms, where it's found

Geological setting

Low temperature borate evaporite.

As above

Type locality
Baker Mine
  1. Rio Tinto Borax Mine
  2. Kramer Borate deposit
  3. Boron
  4. Kern County
  5. California
  6. USA
5recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous/Sub-Adamantine
Transparency
Translucent
Colour
Cinnabar red · darkening on exposure
Streak
Bright cinnabar red
Tenacity
brittle
Cleavage
Perfect

Perfect on (010) and (100); poor on (001).

Fracture
None observed
Density
3.62 g/cm³

Optical

Optical type
Biaxial
Refractive index
2.1
Surface relief
Very high
Principal indices
nβ 2.1
Pleochroism
Weak

X = salmon red, Y = Z = deep blood red.

Dispersion
r < v extreme
Notes

Refractive indices > 2.0

Crystallography

Crystal system
Monoclinic
Space group
Cm
Cell parameters
a = 9.911(8) Å · b = 23.05(2) Å · c = 7.097(8) Å
Cell angles
β = 127.85(7) °
Ratio a:b:c
1 : 2.326 : 0.716
Z
2
Morphology

Fibrous and platy

Type-locality form

Cinnabar-red platy-fibrous spherules, up to 2.5 cm, with a crudely radial fibrous structure, in clay. Also occurs as fine-granular aggregates and as groups of small, thick plates with rough surfaces. The individual crystals of the aggregates are warped an

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
51SbAntimonyAntimony8121.760974.080
47.01%
33AsArsenicArsenic874.922599.376
28.92%
16SSulfurSulfur1332.060416.780
20.11%
11NaSodiumSodium222.99045.980
2.22%
8OOxygenOxygen215.99931.998
1.54%
1HHydrogenHydrogen41.0084.032
0.20%
Total2072.246100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Li

Synonyms

  • Gerstleyiet

In other languages

German
Gerstleyit
Italian
Gerstleyite
Chinese
红硫锑砷钠矿

Classification

Strunz
10th ed.

2.HE.05

  • 2Sulfides and SulfosaltsClass
  • 2.HSulfosalts of SnS archetypeDivision
  • 2.HEWith alkalies, H2OGroup
  • 2.HE.05GerstleyiteSpecies
Dana
8th ed.

03.08.08.01

  • 03SulfosaltsClass
  • 03.081 < ø < 2Type
  • 03.08.08— unnamed intermediate level —Group
  • 03.08.08.01GerstleyiteSpecies
CIM

5.0.1

  • 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
  • 5.0Sulpharsenites etc. of the alkali metalsGroup
  • 5.0.1GerstleyiteSpecies

Literature, links & citation

Citations
  1. Geological Society of America, Program with Abstracts: 11(7): 485.
  2. Chemical Abstracts: 95: 195617y.
  3. 1956Frondel, Clifford, Morgan, Vincent (1956) Inderite and gerstleyite from the Kramer borate district, Kern County, California. American Mineralogist, 41 (11-12) 839-843
  4. 1981Nakai, Izumi, Appleman, Daniel E (1981) The crystal structure of gerstleyite Na2(Sb.As)8S13·2H2O: the first sulfosalt mineral of sodium. Chemistry Letters, 10 (10). 1327-1330 doi:10.1246/cl.1981.1327DOI: 10.1246/cl.1981.1327
  5. 2005(2005) Gerstleyite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Gerstleyite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/gerstleyite-1684},
  note      = {Accessed 2026-05-11}
}