Ghiaraite

CaCl2 · 4H2O
IMA status
  • Approved
IMA symbol
Ghi
Also known as
  • Ghiaraiet
  • IMA2012-072

Where it forms, where it's found

Geological setting

Mount Vesuvius, Italy in voids in the ejecta surface that were exposed to volcanic vapors.

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
1recorded occurrences
Source · OpenStreetMap

Physical

Density
1.838 g/cm³

Optical

Optical type
Biaxial (-)
Refractive index
1.53 – 1.567
Surface relief
Moderate
Principal indices
nα 1.530 · nβ 1.557 · nγ 1.567
Notes

From synthetic material

Michel-Lévy diagramhighlighted lineδ = 0.0370
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]370 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation370 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 6.3660 Å · b = 6.5914 Å · c = 8.5568 Å
Cell angles
α = 93.504 ° · β = 97.778 ° · γ = 110.557 °
Ratio a:b:c
1 : 1.035 : 1.344
Z
2
Type-locality form

Euhedral isometric very small grains (up to 5–6 μm long) intimately intermixed with chlorocalcite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
17ClChlorineChlorine235.45070.900
38.73%
8OOxygenOxygen415.99963.996
34.96%
20CaCalciumCalcium140.07840.078
21.90%
1HHydrogenHydrogen81.0088.064
4.41%
Total183.038100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ghiaraiet
  • IMA2012-072

In other languages

German
Ghiarait · IMA 2012-072
Italian
ghiaraite

Classification

Strunz
10th ed.

3.BB.40

  • 3HalidesClass
  • 3.BSimple halides, with H2ODivision
  • 3.BBM:X = 1:2Group
  • 3.BB.40GhiaraiteSpecies

Literature, links & citation

Citations
  1. 2013Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2013) IMA Commission on New Minerals, Nomenclature and Classification. CNMNC Newsletter No. 15. Mineralogical Magazine, 77 (1) 1-12 doi:10.1180/minmag.2013.077.1.01DOI: 10.1180/minmag.2013.077.1.01
  2. 2014Rossi, M., Nestola, F., Zorzi, F., Lanza, A., Peruzzo, L., Guastoni, A., Kasatkin, A. (2014) Ghiaraite: A new mineral from Vesuvius volcano, Naples (Italy) American Mineralogist, 99 (2) 519-524 doi:10.2138/am.2014.4600 DOI: 10.2138/am.2014.4600
  3. 2017(2017) Ghiaraite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ghiaraite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ghiaraite-43592},
  note      = {Accessed 2026-05-11}
}