Graeserite

Fe3+4Ti3As3+O13(OH)
IMA status
  • Approved
IMA symbol
Gsr
Also known as
  • Graeseriet
  • IMA1996-010

Where it forms, where it's found

Geological setting

In hydrothermal veins in a two-mica paragneiss.

Metamorphosed Precambrian calc-silicate gneissic rock in the footwall of a Zn-Fe-Mn orebody (Sterling Hill, NJ).

Type locality
Gorb
  1. Lärchultini
  2. Binn
  3. Goms
  4. Valais
  5. Switzerland

46.3638°, 8.2280°

3recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789105.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Transparency
Opaque
Colour
Black
Streak
Black
Tenacity
malleable
Cleavage
Distinct/Good

Moderate on (100).

Fracture
Conchoidal
Density
4.56 g/cm³

Optical

Pleochroism
Non-pleochroic
Optical colour
Grayish white.
Bireflectance
None.
Internal reflections
None.
Tropism
Anisotropic
Reflectance R%
(20.1,20.8) 460, (19.6,20.3) 480, (18.7,19.3) 540, (18.2,18.9) 580, (17.5,18.1) 660
Notes

A full-spectrum reflectance plot given in Krzemnicki and Reusser (1998).

Reflected-light panel
18.8 %anisotropic · dual curve
Specimen sRGB 156, 111, 63
White reference100 % reflector under same lamp
R₁ R₂
Mode
Bireflectance
None.
Reflected colour
Grayish white.
Internal reflections
None.

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 5.0225(7) Å · b = 14.3114(18) Å · c = 7.1743(9) Å
Cell angles
β = 104.878(3) °
Ratio a:b:c
1 : 2.849 : 1.428
Unit cell volume
498.39 ų
Twinning

Common, parallel to c axis.

Type-locality form

Needle-shaped (<10 µm thick, up to 5 mm long). Occasionally, occurs in radial aggregates.

Comment

example, Biagoni et al. (2020)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1415.999223.986
33.59%
26FeIronIron455.845223.380
33.50%
22TiTitaniumTitanium347.867143.601
21.53%
33AsArsenicArsenic174.92274.922
11.23%
1HHydrogenHydrogen11.0081.008
0.15%
Total666.897100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Graeseriet
  • IMA1996-010

In other languages

German
Graeserit · IMA 1996-010
Italian
Graeserite
Chinese
砷铁钛矿

Classification

Strunz
10th ed.

4.JB.55

  • 4OxidesClass
  • 4.JArsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodatesDivision
  • 4.JBArsenites, antimonites, bismuthites; with additional anions, without H2OGroup
  • 4.JB.55GraeseriteSpecies

Literature, links & citation

Citations
  1. 1998Krzemnicki, M.S. and Reusser, E. (1998) Graeserite, Fe4Ti3AsO13(OH), a new mineral species of the derbylite group from the Monte Leone Nappe, Binntal region, Western Alps, Switzerland. The Canadian Mineralogist: 36: 1083–1088.
  2. 1998Berlepsch, P. and Armbruster, T. (1998) The crystal structure of Pb2+–bearing graeserite, Pb0.14(Fe,Ti)7AsO12+x(OH)2–x, a mineral of the derbylite group. Schweizerische Mineralogische und Petrographische Mitteilungen: 78: 1–9.
  3. 2006Verbeek, E., Orosz, J., and Nikischer, T. (2006) Graeserite: a second world occurrence from Sterling Hill, Ogdensburg, New Jersey. Mineral News: 22(9): 8-9.
  4. 2020Biagioni, Cristian, Bonaccorsi, Elena, Perchiazzi, Natale, Hålenius, Ulf, Zaccarini, Federica (2020) Derbylite and graeserite from the Monte Arsiccio mine, Apuan Alps, Tuscany, Italy: occurrence and crystal-chemistry. Mineralogical Magazine, 84 (5) 766-777 doi:10.1180/mgm.2020.67DOI: 10.1180/mgm.2020.67
  5. 2022(2022) Graeserite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Graeserite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/graeserite-6977},
  note      = {Accessed 2026-05-11}
}