Grandreefite

Pb2(SO4)F2
IMA status
  • Approved
IMA symbol
Grf
Discovered
1980
IMA approved
1988
Also known as
  • Grandreefiet
  • IMA1988-016

Where it forms, where it's found

Geological setting

Epithermal lead-copper-silver deposit, which is hosted by a silicified breccia.

Type locality
Grand Reef Mine
  1. Laurel Canyon
  2. Grand Reef Mountain
  3. Klondyke
  4. Aravaipa Mining District
  5. Graham County
  6. Arizona
  7. USA

32.8825°, -110.3175°

3recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
Conchoidal
Density
7.0 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 23° · 2V calc = 24°
Refractive index
1.872 – 1.897
Surface relief
Very high
Principal indices
nα 1.872 · nβ 1.873 · nγ 1.897
Dispersion
very strong
Extinction
X = c, Y = a, Z = b.
UV response
None observed.
Michel-Lévy diagramhighlighted lineδ = 0.0250
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]250 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation250 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 8.667(1) Å · b = 4.4419(6) Å · c = 14.242(2) Å
Cell angles
β = 107.418(2) °
Ratio a:b:c
1 : 0.513 : 1.643
Z
4
Morphology

Prismatic and striated parallel to [001]. The forms {l20}, {l30}, (293), {2-93}, and {l01} were present.

Twinning

Coarse polysynthetic twins of undetermined law observed only in transmitted light under crossed polars.

Type-locality form

Isolated prismatic crystals

Comment

Space group A2/a.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead2207.200414.400
75.56%
8OOxygenOxygen415.99963.996
11.67%
9FFluorineFluorine218.99837.996
6.93%
16SSulfurSulfur132.06032.060
5.84%
Total548.452100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Grandreefiet
  • IMA1988-016

In other languages

German
Grandreefit · IMA 1988-016
Italian
Grandreefite

Classification

Strunz
10th ed.

7.BD.45

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BDWith only large cationsGroup
  • 7.BD.45GrandreefiteSpecies
Dana
8th ed.

12.01.02.01

  • 12Compound HalidesClass
  • 12.01MiscellaneousType
  • 12.01.02— unnamed intermediate level —Group
  • 12.01.02.01GrandreefiteSpecies
CIM

26.22

  • 26Sulphates with HalideClass
  • 26.22— unnamed intermediate level —Group
  • 26.22GrandreefiteSpecies

Literature, links & citation

Citations
  1. 1989Kampf, Anthony R., Dunn, Pete J., Foord, Eugene E. (1989) Grandreefite, pseudograndreefite, laurelite, and aravaipaite: Four new minerals from the Grand Reef mine, Graham County, Arizona. American Mineralogist, 74 (7-8) 927-933
  2. 1991Kampf, Anthony R. (1991) Grandreefite, Pb2F2SO4: Crystal structure and relationship to the lanthanide oxide sulfates, Ln2O2SO4. American Mineralogist, 76 (1-2) 278-282
  3. 1996Foord, Eugene E., Kampf, Anthony R. (1996) Calcioaravaipaite, a New Mineral, and Associated Lead Fluoride Minerals from the Grand Reef Mine, Graham County, Arizona. The Mineralogical Record, 27 (4) 293-300
  4. 2005(2005) Grandreefite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Grandreefite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/grandreefite-1738},
  note      = {Accessed 2026-05-11}
}