Grigorievite

Cu3Fe3+2Al2(VO4)6
IMA status
  • Approved
IMA symbol
Ggv
Also known as
  • Grigorieviet
  • IMA2012-047

Where it forms, where it's found

Geological setting

Second scoria cone, Tolbachik volcano, Kamchatka Peninsula, Kamchatka Oblast’, Far- Eastern Region, Russia (55º41’N 160º14’E).

Type locality
Second scoria cone
  1. Northern Breakthrough (North Breach)
  2. Great Fissure eruption (Main Fracture)
  3. Tolbachik Volcanic field
  4. Milkovsky District
  5. Kamchatka Krai
  6. Russia

55.6878°, 160.2435°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Black
Streak
Reddish-brown
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
3.67 g/cm³

Optical

Pleochroism
Non-pleochroic
Optical colour
Grey
Anisotropism
Weak
Bireflectance
Weak
Internal reflections
Weak, deep red
Tropism
Anisotropic
Reflectance R%
(17.3,17.7) 400, (17.0,17.4) 420, (16.8,17.1) 440, (16.5,16.9) 460, (16.4,16.8) 470, (16.3,16.7) 480, (16.1,16.5) 500, (15.9,16.2) 520, (15.6,16.0) 540, (15.5,15.9) 546, (15.4,15.7) 560, (15.0,15.4) 580, (14.9,15.3) 589, (14.8,15.2) 600, (14.5,15.0) 620, (14.2,14.7) 640, (14.1,14.8) 650, (13.9,14.4) 660, (13.7,14.1) 680, (13.5,13.9) 700
Reflected-light panel
15.4 %anisotropic · dual curve
Specimen sRGB 142, 102, 57
White reference100 % reflector under same lamp
R₁ R₂
Mode
Bireflectance
Weak
Anisotropism
Weak
Reflected colour
Grey
Internal reflections
Weak, deep red

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 8.0217 Å · b = 9.6858 Å · c = 6.5475 Å
Cell angles
α = 103.645 ° · β = 102.369 ° · γ = 106.281 °
Ratio a:b:c
1 : 1.207 : 0.816
Type-locality form

Prismatic to thick tabular crystals up to 40 x 100 μm (typically less than 50 μm) in size.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2415.999383.976
36.71%
23VVanadiumVanadium650.942305.652
29.22%
29CuCopperCopper363.546190.638
18.23%
26FeIronIron255.845111.690
10.68%
13AlAluminiumAluminium226.98253.964
5.16%
Total1045.920100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Grigorieviet
  • IMA2012-047

In other languages

German
Grigorievit · IMA 2012-047
Italian
grigorievite

Classification

Strunz
10th ed.

8.AC.02

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ACWith medium-sized and large cationsGroup
  • 8.AC.02GrigorieviteSpecies

Group, growth & confusion

In the same group
4 members

Literature, links & citation

Citations
  1. 2013Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2013) IMA Commission on New Minerals, Nomenclature and Classification. CNMNC Newsletter No. 15. Mineralogical Magazine, 77 (1) 1-12 doi:10.1180/minmag.2013.077.1.01DOI: 10.1180/minmag.2013.077.1.01
  2. 2014Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Kartashov, Pavel M., Polekhovsky, Yury S., Murashko, Mikhail N., Pushcharovsky, Dmitry Y. (2014) Koksharovite, CaMg2Fe3+4(VO4)6, and grigorievite, Cu3Fe3+2Al2(VO4)6, two new howardevansite-group minerals from volcanic exhalations. European Journal of Mineralogy, 26 (5) 667-677 doi:10.1127/0935-1221/2014/0026-2400 DOI: 10.1127/0935-1221/2014/0026-2400
  3. 2015(2015) Grigorievite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Grigorievite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/grigorievite-43572},
  note      = {Accessed 2026-05-11}
}