Guanacoite

Cu2Mg3(OH)4(AsO4)2 · 4H2O
IMA status
  • Approved
IMA symbol
Gnc
Discovered
1997
IMA approved
2003
Also known as
  • Guanacoiet
  • IMA2003-021

Where it forms, where it's found

Type locality
Guanaco Mine
  1. Taltal
  2. Antofagasta Province
  3. Antofagasta
  4. Chile

-25.1023°, -69.5373°

5recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Blue to pale blue
Streak
White to pale blue
Tenacity
brittle
Cleavage
Distinct/Good

Parallel to (010)

Fracture
Irregular/Uneven · Conchoidal
Density
3.31 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 31° · 2V calc = 42°
Refractive index
1.664 – 1.695
Surface relief
High
Principal indices
nα 1.664 · nβ 1.691 · nγ 1.695
Pleochroism
Non-pleochroic
Dispersion
r > v, weak
Extinction
X ∼ c; Y ∧ a = 10° (in obtuse β); Z = b.
Michel-Lévy diagramhighlighted lineδ = 0.0310
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]310 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation310 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#14
Cell parameters
a = 5.475(1) Å · b = 16.865(3) Å · c = 6.915(1) Å
Cell angles
β = 99.8(3) °
Ratio a:b:c
1 : 3.080 : 1.263
Unit cell volume
629.2 ų
Z
2
Morphology

Type material is prismatic and elongated along [100]. The dominant form is (031), terminated by (120). The forms (111) and (121) are rare. The crystals from Taghouni are elongated on [100], showing dominant prism (021) and terminated by (100).

Twinning

None observed.

Type-locality form

Prismatic to acicular crystals up to 0.7 mm in length.

Comment

Cell parameters from single-crystal data

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1615.999255.984
41.42%
33AsArsenicArsenic274.922149.844
24.25%
29CuCopperCopper263.546127.092
20.57%
12MgMagnesiumMagnesium324.30572.915
11.80%
1HHydrogenHydrogen121.00812.096
1.96%
Total617.931100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Guanacoiet
  • IMA2003-021

In other languages

German
Guanacoit · IMA 2003-021
Italian
Guanacoite
Russian
Гуанакоит

Classification

Strunz
10th ed.

8.DD.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DDWith only medium-sized cations, (OH, etc.):RO4= 2:1Group
  • 8.DD.10GuanacoiteSpecies
Dana
8th ed.

42.04.01.02

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.04(AB)5(XO4)2Zq·xH2OType
  • 42.04.01Akrochordite GroupGroup
  • 42.04.01.02GuanacoiteSpecies

Group, growth & confusion

In the same group
2 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 2006Witzke, Thomas, Kolitsch, Uwe, Krause, Werner, Wiechowski, Annemarie, Medenbach, Olaf, Kampf, Anthony R., Steele, Ian M., Favreau, Georges (2006) Guanacoite, Cu2Mg2(Mg0.5Cu0.5)(OH)4(H2O)4(AsO4)2, a new arsenate mineral species from the El Guanaco Mine, near Taltal, Chile: Description and crystal structure. European Journal of Mineralogy, 18 (6) 813-821 doi:10.1127/0935-1221/2006/0018-0813 DOI: 10.1127/0935-1221/2006/0018-0813
  2. 2008Kyono, A. (2008) Compositional variability and crystal structural features of guanacoite. American Mineralogist: 93: 501-507.
  3. 2021(2021) Guanacoite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Guanacoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/guanacoite-11511},
  note      = {Accessed 2026-05-11}
}