Guildite

CuFe3+(SO4)2(OH) · 4H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Gdi
Discovered
1928
Also known as
  • Guildiet

Where it forms, where it's found

Geological setting

Burning pyritic ore body.

Type locality
United Verde Mine
  1. Jerome
  2. Verde Mining District
  3. Black Hills (Black Hill Range)
  4. Yavapai County
  5. Arizona
  6. USA

34.7500°, -112.1222°

5recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Translucent
Colour
Brown · yellow
Streak
Pale yellow
Tenacity
brittle
Cleavage
Perfect

On (001) and (100), perfect.

Fracture
Conchoidal
Density
2.72 g/cm³

Optical

Optical type
Biaxial (+)
Refractive index
1.622 – 1.684
Surface relief
High
Principal indices
nα 1.622 – 1.623 · nβ 1.628 – 1.63 · nγ 1.681 – 1.684
Pleochroism
Visible

X = Light yellow; Y = Light yellow; Z = Greenish yellow.

Dispersion
relatively weak
Notes

2V small.

Michel-Lévy diagramhighlighted lineδ = 0.0600
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]600 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation600 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/m
Cell parameters
a = 9.78 Å · b = 7.13 Å · c = 7.26 Å
Cell angles
β = 105.3 °
Ratio a:b:c
1 : 0.729 : 0.742
Morphology

Crystals short prismatic, pseudo-cubic to 5 mm diameter. Forms include (001), (100), (110), (540), (011), and others. The form (010) was not observed in type material.

Type-locality form

Individual crystals varying in size up to 5 mm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1315.999207.987
51.92%
16SSulfurSulfur232.06064.120
16.01%
29CuCopperCopper163.54663.546
15.86%
26FeIronIron155.84555.845
13.94%
1HHydrogenHydrogen91.0089.072
2.27%
Total400.570100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Guildiet

In other languages

German
Guildit
Italian
Guildite
Chinese
四水铜铁矾

Classification

Strunz
10th ed.

7.DC.30

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DCWith only medium-sized cations; chains of edge-sharing octahedraGroup
  • 7.DC.30GuilditeSpecies
Dana
8th ed.

31.09.07.01

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.09(AB)(XO4)Zq·xH2OType
  • 31.09.07— unnamed intermediate level —Group
  • 31.09.07.01GuilditeSpecies
CIM

25.2.23

  • 25SulphatesClass
  • 25.2Sulphates of Cu and AgGroup
  • 25.2.23GuilditeSpecies

Literature, links & citation

Citations
  1. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  2. 1970Laughon, R. B. (1970) New data on guildite. American Mineralogist, 55 (3-4). 502-505
  3. 1978Wan, Che'ng, Ghose, Subrata, Rossman, George R. (1978) Guildite, a layer structure with a new type of ferric hydroxy-sulphate chain and its optical absorption spectra. American Mineralogist, 63 (5-6) 478-483
  4. 2005(2005) Guildite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Guildite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/guildite-1770},
  note      = {Accessed 2026-05-11}
}