Guilleminite

Ba(UO2)3(Se4+O3)2O2 · 3H2O
IMA status
  • Approved
IMA symbol
Gul
Discovered
1965
Also known as
  • Guilleminiet
  • IMA1964-031

Where it forms, where it's found

Geological setting

Oxidized zone of a uranium-selenium-copper deposit.

Type locality
Musonoi Mine
  1. Kolwezi
  2. Mutshatsha
  3. Lualaba
  4. DR Congo

-10.7135°, 25.4454°

4recorded occurrences
Source · OpenStreetMap

Radioactivity

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Bright yellow
Streak
Light yellow
Tenacity
brittle
Cleavage
Perfect

(100) perfect, (010) good.

Density
4.88 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 35° · 2V calc = 32°
Refractive index
1.72 – 1.805
Surface relief
High
Principal indices
nα 1.720 · nβ 1.798 · nγ 1.805
Birefringence
0.085
Pleochroism
Strong

X = bright yellow; Y = yellow; Z = colorless.

Dispersion
r > v strong
Extinction
Parallel. X = c; Y = b; Z = a.
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0850
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]850 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation850 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#34
Cell parameters
a = 7.29 Å · b = 16.87 Å · c = 7.07 Å
Ratio a:b:c
1 : 2.314 : 0.970
Z
2
Morphology

As rectangular crystals, tabular on (010). Forms include (001), (010), (001), and minor (101).

Type-locality form

Canary-yellow coatings and silky masses up to 1 cm2. In geodes, it forms tablets up to 0.4 x 0.2 mm.

Comment

Space group is P21nm

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
92UUraniumUranium3238.029714.087
55.47%
8OOxygenOxygen1715.999271.983
21.12%
34SeSeleniumSelenium278.971157.942
12.27%
56BaBariumBarium1137.327137.327
10.67%
1HHydrogenHydrogen61.0086.048
0.47%
Total1287.387100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Guilleminiet
  • IMA1964-031

In other languages

French
Guilleminite
German
Guilleminit · IMA 1964-031
Italian
Guilleminite

Classification

Strunz
10th ed.

4.JJ.10

  • 4OxidesClass
  • 4.JArsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodatesDivision
  • 4.JJSelenites with additional anions, with H2OGroup
  • 4.JJ.10GuilleminiteSpecies
Dana
8th ed.

34.07.03.01

  • 34Selenites, Tellurites and SulfitesClass
  • 34.07Hydrated Selenites, Tellurites and Sulfites containing Hydroxyl or HalogenType
  • 34.07.03— unnamed intermediate level —Group
  • 34.07.03.01GuilleminiteSpecies
CIM

28.1.9

  • 28Selenites, Selenates, Tellurites, and TelluratesClass
  • 28.1SelenitesGroup
  • 28.1.9GuilleminiteSpecies

Literature, links & citation

Citations
  1. 1965Pierrot, Roland, Toussaint, J., Verbeek, Théodore (1965) La guilleminite, une nouvelle espèce minérale. Bulletin de Minéralogie, 88 (1) 132-135 doi:10.3406/bulmi.1965.5815 DOI: 10.3406/bulmi.1965.5815
  2. 1965Fleischer, Michael (1965) New Mineral Names. American Mineralogist, 50 (11-12) 2096-2111
  3. 1995Cooper, M. A., Hawthorne, F. C. (1995) The crystal structure of guilleminite, a hydrated Ba-U-Se sheet structure. The Canadian Mineralogist, 33 (5) 1103-1109
  4. 1996Jambor, J.L., Pertsev, N.N., Roberts, A.C. (1996) New mineral names. American Mineralogist: 81: 766-770.
  5. 2001Cooper, M. A., Hawthorne, F. C. (2001) Structure topology and hydrogen bonding in marthozite, Cu2+[(UO2)3(SeO3)2O2](H2O)8, a comparison with guilleminite, Ba[(UO2)3(SeO3)2O2](H2O)3. The Canadian Mineralogist, 39 (3) 797-807 doi:10.2113/gscanmin.39.3.797 DOI: 10.2113/gscanmin.39.3.797
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Guilleminite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/guilleminite-1771},
  note      = {Accessed 2026-05-11}
}