Gwihabaite

(NH4)(NO3)
IMA status
  • Approved
IMA symbol
Gwi
Also known as
  • Gwihabaiet
  • IMA1994-011
  • Nitrammite

Where it forms, where it's found

Geological setting

Caves. Bacterial decay of bat guano.

Caves. In bioremediated soils.

Type locality
Gcwihaba Cave (Drotsky's Caverns)
  1. Ngamiland West District
  2. North-West District
  3. Botswana

-20.0227°, 21.3551°

7recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
Colourless
Streak
White
Cleavage
None Observed
Density
1.77 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 90° · 2V calc = 86°
Refractive index
1.458 – 1.599
Surface relief
Moderate
Principal indices
nα 1.458 · nβ 1.527 · nγ 1.599
Dispersion
none
Notes

X = b, Y = a, Z = c

Michel-Lévy diagramhighlighted lineδ = 0.1410
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1410 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1410 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 7.075 Å · b = 7.647 Å · c = 5.779 Å
Ratio a:b:c
1 : 1.081 : 0.817
Z
4
Morphology

Slender prismatic crystals, divergent aggregates or "cave flowers". Enlongated parallel to [001] and the forms are (110), (100), and (111).

Type-locality form

slender needles and oulopholites, up to 5 mm. long, forming efflorescences on the walls, boulders, bat guano and earthy floor of the cave

Comment

Space Group: P bnm

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen315.99947.997
59.96%
7NNitrogenNitrogen214.00728.014
35.00%
1HHydrogenHydrogen41.0084.032
5.04%
Total80.043100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Gwihabaiet
  • IMA1994-011
  • Nitrammite

In other languages

French
Gwihabaïte
German
Gwihabait · IMA 1994-011
Italian
Gwihabaite

Classification

Strunz
10th ed.

5.NA.15

  • 5CarbonatesClass
  • 5.NNITRATESDivision
  • 5.NAWithout OH or H2OGroup
  • 5.NA.15GwihabaiteSpecies

Literature, links & citation

Citations
  1. 1962Amorós, J.L., Arrese, F., Canut, M. (1962) The crystal structure of the low-temperature phase of NH4NO3 (V) at -150° C. Zeitschrift für Kristallographie: 117: 92-107.
  2. 1996Martini, J.E.J. (1996) Gwihabaite - (NH4,K)NO3, orthorhombic, a new mineral from the Gcwihaba Cave, Botswana. Bulletin of the South African Speleological Association: 36: 19-21.
  3. 1999Jambor, J.L. and Roberts, A.C. (1999) New mineral names. American Mineralogist: 84: 193-198.
  4. 2005(2005) Gwihabaite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Gwihabaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/gwihabaite-6983},
  note      = {Accessed 2026-05-11}
}