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It accepts space group symmetry C2\u002Fc both at room temperature and at 100 K. The specific arrangement of M(1) and M(2) octahedral sites and of P(1) and P(2) tetrahedral sites gives rise to two different channels aligned along the crystallographic c-axis, containing the A(1) and A(2)' sites. The A(1) site is fully occupied and shows a mixed occupation of Na+, Ca2+ and Mn2+ (hagendorfite). The A(2)' is fully occupied by Na+ in hagendorfite.",3.5,"3.71","3.84","Sub-Vitreous,Resinous,Greasy","Translucent","Black to greenish-black",[55,56],"black","green","Not fluorescent.","{010} good; two other cleavages poor.","Distinct\u002FGood","Irregular\u002FUneven","brittle","Biaxial","-","1.708","1.735","1.742","1.722","1.745","66","68","70",1.708,1.745,"r > v","Visible","0.012","X=tan to yellowish green, Z=blue green to grass green.","Granite pegmatite.","Alluaudite Group,  Hagendorfite-Varulite Series.\r\n\r\nNote: Mücke & Keck (2011) propose a new formula: (Na,Ca,Mn)2Mn(Fe2+,Fe3+)2(PO4)3.","Named by Hugo Strunz in 1954 for the locality at Hagendorf, Bavaria, Germany.","2025-08-11 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· H\u003Csub>2\u003C\u002Fsub>O","NaFe\u003Csup>3+\u003C\u002Fsup>\u003Csub>2\u003C\u002Fsub>(Mg,Mn\u003Csup>2+\u003C\u002Fsup>)(AsO\u003Csub>4\u003C\u002Fsub>)\u003Csub>3\u003C\u002Fsub>·H\u003Csub>2\u003C\u002Fsub>O","4.18","4.19",{"id":240,"name":241,"entrytype":9,"csystem":37,"ima_formula":242,"mindat_formula":243,"hmin":38,"hmax":38,"dmeas":244,"dcalc":245,"primary_image_id":11},50466,"Zhanghuifenite","Na\u003Csub>3\u003C\u002Fsub>Mn\u003Csup>2+\u003C\u002Fsup>\u003Csub>4\u003C\u002Fsub>Mg\u003Csub>2\u003C\u002Fsub>Al(PO\u003Csub>4\u003C\u002Fsub>)\u003Csub>6\u003C\u002Fsub>","Na\u003Csub>3\u003C\u002Fsub>Mn\u003Csub>4\u003C\u002Fsub>Mg\u003Csub>2\u003C\u002Fsub>Al(PO\u003Csub>4\u003C\u002Fsub>)\u003Csub>6\u003C\u002Fsub>","3.63","3.62",{"id":247,"name":248,"entrytype":9,"csystem":37,"ima_formula":249,"mindat_formula":250,"hmin":11,"hmax":11,"dmeas":11,"dcalc":251,"primary_image_id":11},50339,"Zincobradaczekite","NaCuCuZn\u003Csub>2\u003C\u002Fsub>(AsO\u003Csub>4\u003C\u002Fsub>)\u003Csub>3\u003C\u002Fsub>","NaZn\u003Csub>2\u003C\u002Fsub>Cu\u003Csub>2\u003C\u002Fsub>(AsO\u003Csub>4\u003C\u002Fsub>)\u003Csub>3\u003C\u002Fsub>","4.71",[],[],[255],{"id":256,"txt":257,"latitude":258,"longitude":259,"country":260},1769,"Hagendorf South Pegmatite, Hagendorf, Waidhaus, Neustadt an der Waldnaab District, Upper Palatinate, Bavaria, Germany",49.6502778,12.4597222,"Germany",18,[263,268,272,276,280,284,288,293,297,302,307,311,316],{"id":264,"year":265,"html":266,"doi":267},438267,1942,"Mason, Brian (1942) Some iron-manganese phosphate minerals from the pegmatite at Hühnerkobel in Bavaria. \u003Ci>Geologiska Föreningen i Stockholm Förhandlingar\u003C\u002Fi>,  64 (3) 335-340 \u003Ca target='_blank' href='https:\u002F\u002Fdoi.org\u002F10.1080\u002F11035894209446083'>doi:10.1080\u002F11035894209446083\u003C\u002Fa>","10.1080\u002F11035894209446083",{"id":269,"year":270,"html":271,"doi":11},16111221,1946,"Eriksson, T. (1946) Triphylite and arrojadite from Norro muscovite pegmatite. Arkiv för Kemi, Mineralogi och Geologi, Stockholm: 23A, no. 8.",{"id":273,"year":274,"html":275,"doi":11},521954,1950,"Lindberg, Marie Louise (1950) Arrojadite, hühnerkobelite, and graftonite. \u003Ci>American Mineralogist\u003C\u002Fi>,  35 (1-2) 59-76 \u003Ca target='_blank' href='http:\u002F\u002Fwww.minsocam.org\u002Fammin\u002FAM35\u002FAM35_59.pdf' class='refpdflink'>\u003C\u002Fa>",{"id":277,"year":278,"html":279,"doi":11},1118652,1951,"Palache, Charles; Berman, Harry; Frondel, Clifford (1951) \u003Ci>The System of Mineralogy\u003C\u002Fi> (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.",{"id":281,"year":282,"html":283,"doi":11},16111224,1954,"Strunz, H. (1954) Hagendorfit, ein neues mineral der Varulith-Hühnerkobelit-Reihe. Neues Jahrbuch für Mineralogie, Monatshefte: 1954: 252-255.",{"id":285,"year":286,"html":287,"doi":11},522655,1955,"Fleischer, M. (1955) New mineral names. \u003Ci>American Mineralogist\u003C\u002Fi>,  40 (5-6). 551-554 \u003Ca target='_blank' href='http:\u002F\u002Fwww.minsocam.org\u002Fammin\u002FAM40\u002FAM40_551.pdf' class='refpdflink'>\u003C\u002Fa>",{"id":289,"year":290,"html":291,"doi":292},3015,1979,"Moore, Paul B., Ito, Jun (1979) Alluaudites, wyllieites, arrojadites: crystal chemistry and nomenclature. \u003Ci>Mineralogical Magazine\u003C\u002Fi>,  43 (326) 227-235 \u003Ca target='_blank' href='https:\u002F\u002Fdoi.org\u002F10.1180\u002Fminmag.1979.043.326.04'>doi:10.1180\u002Fminmag.1979.043.326.04\u003C\u002Fa> \u003Ca target='_blank' href='https:\u002F\u002Frruff.info\u002Fdoclib\u002FMinMag\u002FVolume_43\u002F43-326-227.pdf' class='refpdflink'>\u003C\u002Fa>","10.1180\u002Fminmag.1979.043.326.04",{"id":294,"year":295,"html":296,"doi":11},16964711,2005,"(2005) Hagendorfite. \u003Ci>Handbook of Mineralogy\u003C\u002Fi>. Mineralogical Society of America \u003Ca target='_blank' href='https:\u002F\u002Fwww.handbookofmineralogy.org\u002Fpdfs\u002Fhagendorfite.pdf' class='refpdflink'>\u003C\u002Fa>",{"id":298,"year":299,"html":300,"doi":301},128505,2006,"Redhammer, Günther J., Tippelt, Gerold, Bernroider, Manfred, Lottermoser, Werner, Amthauer, Georg, Roth, Georg (2006) Hagendorfite (Na,Ca)MnFe\u003Csub>2\u003C\u002Fsub>(PO\u003Csub>4\u003C\u002Fsub>)\u003Csub>3\u003C\u002Fsub> from type locality Hagendorf (Bavaria, Germany): crystal structure determination and 57Fe Mossbauer spectroscopy. \u003Ci>European Journal of Mineralogy\u003C\u002Fi>,  17 (6) 915-932 \u003Ca target='_blank' href='https:\u002F\u002Fdoi.org\u002F10.1127\u002F0935-1221\u002F2005\u002F0017-0915'>doi:10.1127\u002F0935-1221\u002F2005\u002F0017-0915\u003C\u002Fa>","10.1127\u002F0935-1221\u002F2005\u002F0017-0915",{"id":303,"year":304,"html":305,"doi":306},16560438,2009,"Łodziński, M., Sitarz, M. (2009) Chemical and spectroscopic characterization of some phosphate accessory minerals from pegmatites of the Sowie Góry Mts, SW Poland. \u003Ci>Journal of Molecular Structure\u003C\u002Fi>,  924-926. 442-447 \u003Ca target='_blank' href='https:\u002F\u002Fdoi.org\u002F10.1016\u002Fj.molstruc.2008.11.019'>doi:10.1016\u002Fj.molstruc.2008.11.019\u003C\u002Fa>","10.1016\u002Fj.molstruc.2008.11.019",{"id":308,"year":309,"html":310,"doi":11},15953978,2011,"Mücke, A. & Keck, E. (2011): Karbonate aus dem Pegmatit von Hagendorf-Süd\u002FOpf.: Zusammensetzung, Verbreitung und begleitende Phosphat-Mineralien (Apatit, Hagendorfit und Eosphorit-Gruppe) - darunter einige Neufunde (Triplit, Mineralien der Arrojadit-Dickinsonit Reihe, Goyazit und Variscit). Aufschluss 62, 87-117.",{"id":312,"year":313,"html":314,"doi":315},397531,2014,"Dyar, M. D., Jawin, E. R., Breves, E., Marchand, G., Nelms, M., Lane, M. D., Mertzman, S. A., Bish, D. L., Bishop, J. L. (2014) Mössbauer parameters of iron in phosphate minerals: Implications for interpretation of martian data. \u003Ci>American Mineralogist\u003C\u002Fi>,  99 (5) 914-942 \u003Ca target='_blank' href='https:\u002F\u002Fdoi.org\u002F10.2138\u002Fam.2014.4701'>doi:10.2138\u002Fam.2014.4701\u003C\u002Fa>","10.2138\u002Fam.2014.4701",{"id":317,"year":318,"html":319,"doi":320},13664665,2021,"Tait, Kimberly T., Hawthorne, Frank C., Halden, Norman M. (2021) Alluaudite-Group Phosphate and Arsenate Minerals. \u003Ci>The Canadian Mineralogist\u003C\u002Fi>, 59 (1) 243-263 \u003Ca target='_blank' href='https:\u002F\u002Fdoi.org\u002F10.3749\u002Fcanmin.2000057'>doi:10.3749\u002Fcanmin.2000057\u003C\u002Fa>","10.3749\u002Fcanmin.2000057",[322,331,338],{"id":323,"source_url":324,"license_code":325,"credit_html":326,"title":327,"description":328,"author":329,"original_width":330,"original_height":330},10691,"https:\u002F\u002Fcommons.wikimedia.org\u002F?curid=10438746","CC BY-SA 3.0","Robert M. Lavinsky, via \u003Ca href=\"https:\u002F\u002Fcommons.wikimedia.org\u002F?curid=10438746\" rel=\"noopener\">Wikimedia Commons\u003C\u002Fa>","Hagendorfite-sea78c.jpg","\u003Ca href=\"https:\u002F\u002Fen.wikipedia.org\u002Fwiki\u002FHagendorfite\" class=\"extiw\" title=\"en:Hagendorfite\">Hagendorfite\u003C\u002Fa>\n\u003Cdl>\u003Cdd>\u003Cdl>\u003Cdd>Locality: Siglo Veinte Mine (Siglo XX Mine; Llallagua Mine; Catavi), \u003Ca href=\"https:\u002F\u002Fen.wikipedia.org\u002Fwiki\u002FLlallagua\" class=\"extiw\" title=\"en:Llallagua\">Llallagua\u003C\u002Fa>, \u003Ca href=\"https:\u002F\u002Fen.wikipedia.org\u002Fwiki\u002FRafael_Bustillo_Province\" class=\"extiw\" title=\"en:Rafael Bustillo Province\">Rafael Bustillo Province\u003C\u002Fa>, \u003Ca href=\"https:\u002F\u002Fen.wikipedia.org\u002Fwiki\u002FPotos%C3%AD_Department\" class=\"extiw\" title=\"en:Potosí Department\">Potosí Department\u003C\u002Fa>, Bolivia (\u003Ca rel=\"nofollow\" class=\"external text\" href=\"http:\u002F\u002Fwww.mindat.org\u002Floc-336.html\">Locality at mindat.org\u003C\u002Fa>)\u003C\u002Fdd>\n\u003Cdd>Size: thumbnail, 1.8 x 1.4 x 0.9 cm\n\u003Cdl>\u003Cdt>Hagendorfite\u003C\u002Fdt>\u003C\u002Fdl>\u003C\u002Fdd>\n\u003Cdd>Hagendorfite is a rare iron phosphate, and I personally have never seen one. However, this is an old piece purchased from David New's famous old mail order species lists, in 1976. Although small, it seems rich and well-crystallized with sharp clusters of crystals to 4mm. There is a hint of green-brown color, in person. Ex. John White Collection.\u003C\u002Fdd>\u003C\u002Fdl>\u003C\u002Fdd>\u003C\u002Fdl>","Robert M. Lavinsky",661,{"id":332,"source_url":333,"license_code":325,"credit_html":334,"title":335,"description":328,"author":329,"original_width":336,"original_height":337},10692,"https:\u002F\u002Fcommons.wikimedia.org\u002F?curid=10438750","Robert M. Lavinsky, via \u003Ca href=\"https:\u002F\u002Fcommons.wikimedia.org\u002F?curid=10438750\" rel=\"noopener\">Wikimedia Commons\u003C\u002Fa>","Hagendorfite-sea78b.jpg",756,711,{"id":339,"source_url":340,"license_code":325,"credit_html":341,"title":342,"description":328,"author":329,"original_width":343,"original_height":344},10693,"https:\u002F\u002Fcommons.wikimedia.org\u002F?curid=10438755","Robert M. Lavinsky, via \u003Ca href=\"https:\u002F\u002Fcommons.wikimedia.org\u002F?curid=10438755\" rel=\"noopener\">Wikimedia Commons\u003C\u002Fa>","Hagendorfite-sea78a.jpg",688,800,[346],{"id":347,"url":348,"label":349,"formula":350,"spacegroup":351,"year":295},5860,"\u002Fcif\u002F5860.cif","Redhammer 2005","Na1.83 Ca.17 Mn Fe2 P3 O12","C 1 2\u002Fc 1",[353,354],"Arrojadite (of Mason)","Hagendorfiet",[356,360,364,368,372],{"lang":357,"names":358},"ca",[359],"hagendorfita",{"lang":361,"names":362},"de",[363],"Hagendorfit",{"lang":365,"names":366},"eu",[367],"Hagendorfita",{"lang":369,"names":370},"lv",[371],"Hāgendorfīts",{"lang":373,"names":374},"pl",[363],"Q5638601",{"history":11,"applications":11}]