Haigerachite

KFe3+3(H2PO4)6(HPO4)2 · 4H2O
IMA status
  • Approved
IMA symbol
Hga
Also known as
  • Haigerachiet
  • IMA1997-049

Where it forms, where it's found

Geological setting

Secondary phosphate formed on dump material.

Type locality
Silberbrünnle Mine
  1. Gengenbach
  2. Gengenbach
  3. Ortenaukreis
  4. Freiburg Region
  5. Baden-Württemberg
  6. Germany

48.4375°, 8.0844°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
White
Streak
White
Cleavage
Distinct/Good

(001)

Fracture
Irregular/Uneven
Density
2.44 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 32° · 2V calc = 34°
Refractive index
1.557 – 1.602
Surface relief
Moderate
Principal indices
nα 1.557 · nβ 1.598 · nγ 1.602
Pleochroism

X perpendicular to (001)

Dispersion
relatively weak
Michel-Lévy diagramhighlighted lineδ = 0.0450
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]450 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation450 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#10
Cell parameters
a = 16.95(3) Å · b = 9.59(2) Å · c = 17.57(3) Å
Cell angles
β = 90.85 °
Ratio a:b:c
1 : 0.566 : 1.037
Z
4
Morphology

Thin tabular, pseudohexagonal crystals flattened (001), showing (100) and (110).

Type-locality form

White spherules, to 0.2 mm across, consisting of scaly crystals to 0.05 mm; rarely as well-developed, thin tabular, pseudohexagonal crystals.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3615.999575.964
54.72%
15PPhosphorusPhosphorus830.974247.792
23.54%
26FeIronIron355.845167.535
15.92%
19KPotassiumPotassium139.09839.098
3.71%
1HHydrogenHydrogen221.00822.176
2.11%
Total1052.565100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Haigerachiet
  • IMA1997-049

In other languages

German
Haigerachit · IMA 1997-049
Italian
Haigerachite

Classification

Strunz
10th ed.

8.CF.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CFWith large and medium-sized cations, RO4:H2O > 1:1Group
  • 8.CF.10HaigerachiteSpecies

Literature, links & citation

Citations
  1. 1987Waerstad, Kjell R., Frazier, A. William (1987) X-Ray Powder Diffraction and Single-Crystal Data for the Isomorphous Series (Fe,Al)3(K,NH4,H3O)H14(PO4)8·4H2O. Powder Diffraction, 2 (3). 187-190 doi:10.1017/s0885715600012689DOI: 10.1017/s0885715600012689
  2. 1997Anisimova, N., Chudinova, N., Serafin, M. (1997) Preparation and Crystal Structure of Potassium Iron Hydrogen Phosphate, KFe3(HPO4)2(H2PO4)6 · 4 H2O. Zeitschrift für anorganische und allgemeine Chemie, 623 (11). 1708-1714 doi:10.1002/zaac.19976231106DOI: 10.1002/zaac.19976231106
  3. 1999Walenta, K., Theye, Th. (1999) Haigerachit, ein neues Phosphatmineral von der Grube Silberbrünnle bei Gengenbach im mittleren Schwarzwald. Aufschluss: 50: 1-7.
  4. 2021(2021) Haigerachite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Haigerachite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/haigerachite-6985},
  note      = {Accessed 2026-05-11}
}