Hannebachite

Ca(SO3) · 0.5H2O
IMA status
  • Approved
IMA symbol
Hbc
Discovered
1983
IMA approved
1983
Also known as
  • Hannebachiet
  • IMA1983-056

Where it forms, where it's found

Geological setting

In cavities in melilite-nepheline-leucite lava at a Quarternary volcano. Thought to be a primary mineral.

Type locality
Hannebacher Ley
  1. Hannebach
  2. Spessart
  3. Brohltal
  4. Ahrweiler
  5. Rhineland-Palatinate
  6. Germany

50.4483°, 7.1392°

14recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
Colourless · white
Streak
White
Cleavage
Perfect

(110)

Density
2.52 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 38° · 2V calc = 40°
Refractive index
1.596 – 1.634
Surface relief
Moderate
Principal indices
nα 1.596 · nβ 1.6 · nγ 1.634
Dispersion
r < v weak
Extinction
Parallel. X = a; Y = c; Z = b.
Michel-Lévy diagramhighlighted lineδ = 0.0380
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]380 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation380 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 6.473(5) Å · b = 9.782(9) Å · c = 10.646(9) Å
Ratio a:b:c
1 : 1.511 : 1.645
Z
4
Morphology

Crystals elongate [010], flattened on (001) and modified by {l01} and (021).

Type-locality form

Crystals up to q mm long, elongate on [010] and flattened (001).

Comment

Non-standard space-group setting Pbna.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3.515.99955.997
43.36%
20CaCalciumCalcium140.07840.078
31.03%
16SSulfurSulfur132.06032.060
24.83%
1HHydrogenHydrogen11.0081.008
0.78%
Total129.143100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Hannebachiet
  • IMA1983-056

In other languages

German
Hannebachit
Italian
Hannebachite

Classification

Strunz
10th ed.

4.JE.10

  • 4OxidesClass
  • 4.JArsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodatesDivision
  • 4.JESulfitesGroup
  • 4.JE.10HannebachiteSpecies
Dana
8th ed.

34.02.05.01

  • 34Selenites, Tellurites and SulfitesClass
  • 34.02A(XO3)·xH2OType
  • 34.02.05— unnamed intermediate level —Group
  • 34.02.05.01HannebachiteSpecies
CIM

27.1.1

  • 27Sulphites, Chromates, Molybdates and TungstatesClass
  • 27.1SulphitesGroup
  • 27.1.1HannebachiteSpecies

Literature, links & citation

Citations
  1. 1973Schröpfer, L. (1973): Strukturelle Untersuchungen am CaSO3·1/2H2O. Zeitschrift für Anorganische und Allgemeine Chemie, 401, 1-14.
  2. 1985Hentschel, G., Tillmanns, E., Hofmeister, W. (1985): Hannebachite, natural calciumsulfite hemihydrate, CaSO3.1/2H2O. Neues Jahrbuch für Mineralogie, Monatshefte, 1985, 241-250.
  3. 1988Jambor, John L.; Bladh, Kenneth W.; Ercit, T. Scott; Grice, Joel D.; Grew, Edward S. (1988) New mineral names. American Mineralogist, 73 (7-8). 927-935
  4. 2005(2005) Hannebachite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2008Postl, W., Bernhard, F. & Bojar, H.-P. (2008): Hannebachit aus dem Steinbruch am Stradner Kogel bei Wilhelmsdorf, Steiermark - erster Nachweis eines Sulfits in Österreich. Joannea - Mineralogie, 4, 115-125. [http://www.zobodat.at/pdf/JoanneaMineralogie_4_0115-0125.pdf]
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hannebachite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hannebachite-1997},
  note      = {Accessed 2026-05-11}
}