Hartkoppeite

Ca4Mn2+Mo6+6As5+4O32(OH)2(H2O)14·5H2O
IMA status
  • Approved
  • Pending publication
IMA symbol
Hkp
Also known as
  • Hartkoppeiet
  • IMA2025-056

Where it forms, where it's found

Geological setting

Fuchs quarry exploits hydrothermal Mn-Fe-As-rich veins in a rhyolite body. A late-stage, low-temperature supergene mineral in an arsenic-rich vein.

Type locality
Fuchs Quarry
  1. Hartkoppe
  2. Sailauf
  3. Aschaffenburg District
  4. Lower Franconia
  5. Bavaria
  6. Germany

50.0336°, 9.2731°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
colorless
Streak
white
Tenacity
brittle
Cleavage
Very Good

(110) very good, (011) and (110)

Fracture
Step-Like
Density
2.88 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 22° · 2V calc = 22.9°
Refractive index
1.692 – 1.718
Surface relief
High
Principal indices
nα 1.692 · nβ 1.693 · nγ 1.718
Pleochroism
Non-pleochroic
Dispersion
r<v
UV response
none in long or short wave UV
Michel-Lévy diagramhighlighted lineδ = 0.0260
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]260 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation260 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 13.34610(15) Å · b = 13.53840(12) Å · c = 14.3087(2) Å
Cell angles
α = 71.080(5) ° · β = 82.936(6) ° · γ = 68.792(5) °
Ratio a:b:c
1 : 1.014 : 1.072
Z
2
Twinning

none

Type-locality form

elongated and striated tabular crystals up to about 0.2 mm long. Tablets are flattened on (110), elongated and striated parallel to [001], and exhibit the forms (110), (110), and (001)

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen5315.999847.947
42.85%
42MoMolybdenumMolybdenum695.950575.700
29.09%
33AsArsenicArsenic474.922299.688
15.14%
20CaCalciumCalcium440.078160.312
8.10%
25MnManganeseManganese154.93854.938
2.78%
1HHydrogenHydrogen401.00840.320
2.04%
Total1978.905100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From Mindat formula

Synonyms

  • Hartkoppeiet
  • IMA2025-056

In other languages

German
Hartkoppeit · IMA 2025-056

Classification

Strunz
10th ed.

7.GB

  • 7SulfatesClass
  • 7.GMolybdates, Wolframates and NiobatesDivision
  • 7.GBWith additional anions and/or H2OGroup
  • 7.GBHartkoppeiteSpecies

Literature, links & citation

Citations
  1. 2025Bosi, Ferdinando; Hatert, Frédéric; Pasero, Marco; Mills, Stuart J. (2025) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) – Newsletter 88. Mineralogical Magazine, 89. 1-11 doi:10.1180/mgm.2025.10183DOI: 10.1180/mgm.2025.10183
  2. 2026Kampf, Anthony R.; Möhn, Gerhard; Ma, Chi; Désor, Joy (2026) Hartkoppeite, a new mineral with a novel polyoxometalate sandwich cluster. American Mineralogist. doi:10.2138/am-2026-10210DOI: 10.2138/am-2026-10210
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hartkoppeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hartkoppeite-498758},
  note      = {Accessed 2026-05-11}
}