Hectorfloresite

Na9(IO3)(SO4)4
IMA status
  • Approved
IMA symbol
Hfl
Discovered
1987
IMA approved
1987
Also known as
  • Hectorfloresiet
  • IMA1987-050a

Where it forms, where it's found

Geological setting

cavities in dense nitrate ore, that is a saline-cemented silt, sand, and small rock fragments; the cavities are dessication fissures, 30 cm in diameter; hectorfloresite is intergrown with glauberite and overgrowths on glauberite and halite

Type locality
Alianza Mine (Rajo No. 13)
  1. Oficina Victoria
  2. Tamarugal Province
  3. Tarapacá
  4. Chile
2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
White

Colourless in transmitted light

Cleavage
None Observed
Fracture
Conchoidal
Density
2.80 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 26° · 2V calc = 28°
Refractive index
1.493 – 1.523
Surface relief
Moderate
Principal indices
nα 1.493 · nβ 1.521 · nγ 1.523
Dispersion
r > v, barely discernible
Michel-Lévy diagramhighlighted lineδ = 0.0300
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]300 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation300 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/a
Cell parameters
a = 18.775(4) Å · b = 6.9356(7) Å · c = 14.239(2) Å
Cell angles
β = 108.91(2) °
Ratio a:b:c
1 : 0.369 : 0.758
Unit cell volume
1754 ų
Z
4
Morphology

Observed forms: (100), (001), (212)

Twinning

multiple, contact, || [010], very often, on (001), (601), and (604) twin planes, giving a pseudohexagonal outline

Parting
irregular, perpendicular and parallel to elongation
Type-locality form

tiny pseudohexagonal prisms, usually below 1 mm in length and 0.2 mm in diameter

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1915.999303.981
39.68%
11NaSodiumSodium922.990206.910
27.01%
16SSulfurSulfur432.060128.240
16.74%
53IIodineIodine1126.904126.904
16.57%
Total766.035100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Hectorfloresiet
  • IMA1987-050a

In other languages

German
Hectorfloresit · IMA1987-050a
Italian
Hectorfloresite
Portuguese
Hectorfloresita · IMA1987-050a

Classification

Strunz
10th ed.

7.BD.60

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BDWith only large cationsGroup
  • 7.BD.60HectorfloresiteSpecies
Dana
8th ed.

32.01.02.01

  • 32Compound SulfatesClass
  • 32.01Anhydrous Compound SulfatesType
  • 32.01.02— unnamed intermediate level —Group
  • 32.01.02.01HectorfloresiteSpecies
CIM

29.8

  • 29IodatesClass
  • 29.8— unnamed intermediate level —Group
  • 29.8HectorfloresiteSpecies

Literature, links & citation

Citations
  1. 1989Ericksen, George E., Evans, Howard T., Jr.,, Mrose, Mary E., Mcgee, James J., Marinenko, John W., Konnert, Judith A. (1989) Mineralogical studies of the nitrate deposits of Chile: VI. Hectorfloresite. Na9(IO3)(SO4)4, a new saline mineral. American Mineralogist, 74 (9-10) 1207-1214
  2. 2005(2005) Hectorfloresite. Handbook of Mineralogy. Mineralogical Society of America
  3. 2016Anthony, John W., Bideaux, Richard A., Bladh, Kenneth W., Nichols, Monte C. - Eds. (2016) Handbook of Mineralogy. https://www.handbookofmineralogy.org/
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hectorfloresite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hectorfloresite-1840},
  note      = {Accessed 2026-05-11}
}